The role of iron(ii) dilution in the magnetic and photomagnetic properties of the series [Fe sub(x)Zn sub(1-x)(bpp) sub(2)](NCSe) sub(2)

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 43; no. 21; pp. 7820 - 7829
• Main Authors: Balde, Cherif, Desplanches, Cedric, Le Gac, Frederic, Guionneau, Philippe, Letard, Jean-Francois
• Format: Journal Article
• Language: English
• Published: 01.05.2014
• Subjects: Conversion; Diffraction; Dilution; Magnetic permeability; Magnetic properties; Mixed crystals; Reflectivity; X-rays

The effects of metal dilution on the spin-crossover behavior of iron(ii) in the mixed crystal series [Fe sub(x)Zn sub(1-x)(bpp) sub(2)](NCSe) sub(2) (bpp = 2,6-bis(pyrazol-3-yl)pyridine) have been studied using magnetic susceptibility, photomagnetism and diffuse reflectivity measurements. For each m...