Co sub(3)O sub(4) microcubes with exceptionally high conductivity using a CoAl layered double hydroxide precursor viasoft chemically synthesized cobalt carbonate
Cubic microparticles of Co sub(3)O sub(4) spinel were synthesized by calcination of CoCO sub(3) obtained using CoAl layered double hydroxide (LDH) as a unitary precursor through soft-chemical decomposition. The obtained cobalt spinel showed an exceptionally high electrical conductivity at room tempe...
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Published in | Journal of materials chemistry. A, Materials for energy and sustainability Vol. 2; no. 18; pp. 6301 - 6304 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
01.04.2014
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Online Access | Get full text |
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Abstract | Cubic microparticles of Co sub(3)O sub(4) spinel were synthesized by calcination of CoCO sub(3) obtained using CoAl layered double hydroxide (LDH) as a unitary precursor through soft-chemical decomposition. The obtained cobalt spinel showed an exceptionally high electrical conductivity at room temperature. This is attributed to high concentrations of charge carriers (Co super(4+)), unique morphology, high reduction temperature and low activation barrier. |
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AbstractList | Cubic microparticles of Co sub(3)O sub(4) spinel were synthesized by calcination of CoCO sub(3) obtained using CoAl layered double hydroxide (LDH) as a unitary precursor through soft-chemical decomposition. The obtained cobalt spinel showed an exceptionally high electrical conductivity at room temperature. This is attributed to high concentrations of charge carriers (Co super(4+)), unique morphology, high reduction temperature and low activation barrier. |
Author | Antonyraj, Churchil A Vinu, Ajayan Srinivasan, Kannan Sankaranarayanan, Sivashunmugam Srivastava, Divesh N Mane, Gurudas P |
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Title | Co sub(3)O sub(4) microcubes with exceptionally high conductivity using a CoAl layered double hydroxide precursor viasoft chemically synthesized cobalt carbonate |
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