Theoretical and super(27)Al CPMAS NMR investigation of aluminum coordination changes during aluminosilicate dissolution
Ab initio molecular orbital calculations were performed, and super(27)Al CP MAS-NMR spectra were evaluated in order to investigate the possible tetrahedral to octahedral coordination change of Al at the feldspar-water interface under acidic conditions. Aluminum coordination is octahedral in solution...
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Published in | Geochimica et cosmochimica acta Vol. 69; no. 9; pp. 2205 - 2220 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
01.05.2005
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Subjects | |
Online Access | Get full text |
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