Ionic Charge Imbalance in Perovskite Solar Cells

Ion migration in perovskite solar cells is usually analyzed and understood in terms of charge neutrality condition. However, several recent reports indicate possibility of ionic imbalance in the active layer due to external ion migration and/or chemical reactions. In this context, here we explore th...

Full description

Saved in:
Bibliographic Details
Published inarXiv.org
Main Authors Sivadas, Dhyana, Singareddy, Abhimanyu, Chittiboina vinod, Nair, Pradeep
Format Paper
LanguageEnglish
Published Ithaca Cornell University Library, arXiv.org 26.01.2023
Subjects
Chemical reactions
Computer architecture
Electrostatics
Interface stability
Ion migration
Perovskites
Photovoltaic cells
Solar cells
Online AccessGet full text

Cover

More Information
Summary:Ion migration in perovskite solar cells is usually analyzed and understood in terms of charge neutrality condition. However, several recent reports indicate possibility of ionic imbalance in the active layer due to external ion migration and/or chemical reactions. In this context, here we explore the influence of ionic charge neutrality on the performance of perovskite solar cells. Our results indicate that ionic imbalance leads to an asymmetry in the device electrostatics, which have interesting implications on the impact of material/interface degradation, hysteresis, and finally on the long-term stability and influence of optimal device architecture (NIP vs. PIN).
ISSN:2331-8422