Designer magnetic topological graphene nanoribbons

• Published in: arXiv.org
• Main Authors: Song, Shaotang, Pei Wen Ng, Shayan Edalatmanesh, Andrés Pinar Solé, Peng, Xinnan, Kolorenč, Jindřich, Sosnová, Zdenka, Stetsovych, Oleksander, Su, Jie, Li, Jing, Sun, Hongli, Liebig, Alexander, Su, Chenliang, Wu, Jishan, Giessibl, Franz J, Jelinek, Pavel, Chi, Chunyan, Lu, Jiong
• Format: Paper
• Language: English
• Published: Ithaca Cornell University Library, arXiv.org 27.04.2022
• Subjects: Chemical synthesis; Chemists; Condensed matter physics; Coupling (molecular); Design; Ferromagnetism; First principles; Graphene; Magnetism; Nanoribbons; Paramagnetism; Quantum Hall effect; Spintronics; Symmetry; Topology

The interplay of magnetism and topology lies at the heart of condensed matter physics, which offers great opportunities to design intrinsic magnetic topological materials hosting a variety of exotic topological quantum states including the quantum anomalous Hall effect (QAHE), axion insulator state, and Majorana bound states. Extending this concept to one-dimension (1D) systems offers additional rich quantum spin physics with great promise for molecular-scale spintronics. Despite recent progress in the discovery of symmetry-protected topological quantum phases in 1D graphene nanoribbons (GNRs), the rational design and realization of magnetic topological GNRs (MT-GNRs) represents a grand challenge, as one must tackle multiple dimensions of complexity including time-reversal symmetry (TRS), spatial symmetry (width, edge, end geometry) and many-electron correlations. Here, we devised a new route involving the real- and reciprocal-space descriptions by unifying the chemists and physicists perspectives, for the design of such MT-GNRs with non-trivial electronic topology and robust magnetic terminal. Classic Clar's rule offers a conceptually qualitative real-space picture to predict the transition from closed-shell to open-shell with terminal magnetism, and band gap reopening with possible non-trivial electronic topology in a series of wave-like GNRs, which are further verified by first principle calculations of band-structure topology in a momentum-space. With the advance of on-surface synthesis and careful design of molecular precursors, we have fabricated these MT-GNRs with observation of topological edge bands, whose terminal pi-magnetism can be directly captured using a single-nickelocene spin sensor. Moreover, the transition from strong anti-ferromagnetic to weak coupling (paramagnetism-like) between terminal spins can be controlled by tuning the length of MT-GNRs.