Measurement of 87Sr/86Sr in limestones after acid leaching and direct injection in a liquid chromatograph coupled to a multicollector ICP-MS
A procedure for the measurement of 87Sr/86Sr in carbonates without off-line strontium separation was developed, validated and applied to Normandy chalkstones. The method is based on the injection of the dissolved/leached sample into a high-performance liquid chromatography (HPLC) system directly cou...
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Published in | Journal of analytical atomic spectrometry Vol. 37; no. 1; pp. 194 - 202 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
London
Royal Society of Chemistry
01.01.2022
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Abstract | A procedure for the measurement of 87Sr/86Sr in carbonates without off-line strontium separation was developed, validated and applied to Normandy chalkstones. The method is based on the injection of the dissolved/leached sample into a high-performance liquid chromatography (HPLC) system directly coupled to a multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS). Matrix and spectral (Ca, Rb) interferences were removed by an on-line separation procedure based on cation exchange chromatography using 1 M nitric acid as an eluent in the presence of 3.8 mM 18-crown-6. The main polyatomic interferent was identified as NO2Ca+, affecting mass 86 of strontium. Isotope ratios were calculated by multiple linear regression from the measured chromatographic peaks. The method was evaluated using a NIST 987 Sr isotope reference material and subsequently validated employing a JCp-1 coral reference material in comparison with the traditional off-line separation procedure. Finally, the method was applied to ten Normandy limestones (chalkstones) with results in agreement with the expected values based on geological, geochemical, and stratigraphic studies. |
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AbstractList | A procedure for the measurement of 87Sr/86Sr in carbonates without off-line strontium separation was developed, validated and applied to Normandy chalkstones. The method is based on the injection of the dissolved/leached sample into a high-performance liquid chromatography (HPLC) system directly coupled to a multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS). Matrix and spectral (Ca, Rb) interferences were removed by an on-line separation procedure based on cation exchange chromatography using 1 M nitric acid as an eluent in the presence of 3.8 mM 18-crown-6. The main polyatomic interferent was identified as NO2Ca+, affecting mass 86 of strontium. Isotope ratios were calculated by multiple linear regression from the measured chromatographic peaks. The method was evaluated using a NIST 987 Sr isotope reference material and subsequently validated employing a JCp-1 coral reference material in comparison with the traditional off-line separation procedure. Finally, the method was applied to ten Normandy limestones (chalkstones) with results in agreement with the expected values based on geological, geochemical, and stratigraphic studies. |
Author | Rodríguez, J Nehme, C Gil-Ibarguchi, J I Ballesteros, D Martín-Izard, A Puente-Berdasco, B Garcia Alonso, J I Mouralis, D Painchault, A |
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Snippet | A procedure for the measurement of 87Sr/86Sr in carbonates without off-line strontium separation was developed, validated and applied to Normandy chalkstones.... |
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SubjectTerms | Acid leaching Carbonates Cation exchanging Chromatography High performance liquid chromatography Inductively coupled plasma mass spectrometry Isotope ratios Nitric acid Reference materials Separation Stratigraphy Strontium Strontium 87 Strontium isotopes |
Title | Measurement of 87Sr/86Sr in limestones after acid leaching and direct injection in a liquid chromatograph coupled to a multicollector ICP-MS |
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