Rationalizing chain microstructure in the poly[alpha]-olefins synthesized by cationic AlCl3/H2O catalytic system

• Published in: International journal of polymer analysis & characterization Vol. 24; no. 6; p. 556
• Main Authors: Sadjadi, Samaheh, Bahri-Laleh, Naeimeh, Nekoomanesh-Haghighi, Mehdi, Ziaee, Farshid, Dehghani, Sedva, Shirbakht, Sedigheh, Rahbar, Ameneh, Barough, Mehdi Salehi, Mirmohammadi, Seyed Amin
• Format: Journal Article
• Language: English
• Published: Philadelphia Taylor & Francis Ltd 01.01.2019
• Subjects: Alkenes; Aluminum chloride; Catalysis; Chemical synthesis; Hydrogenation; Isomerization; Microstructure; Molecular weight; Monomers; Oligomerization; Oligomers; Spectrum analysis

In this study, three middle range α-olefin monomers including 1-hexene, 1-octene, and 1-decene were oligomerized using conventional AlCl3/H2O catalytic system. Molecular weight and microstructure of the oligomers were analyzed by GPC and 1HNMR, respectively. By 1HNMR spectra, both internal (CHR=CHR[...