INVESTIGATION OF THE QUATERNARY AMMONIUM CATION ROLE AND THE SOLVENT EFFECT IN THE PROCESS OF COMPLEX FORMATION OF 1,1,3-TRIMETHYL-3-(4-METHYLPHENYL)BUTYL HYDROPEROXIDE WITH TETRAETHYLAMMONIUM BROMIDES

The formation of a complex between 1,1,3-trimethyl-3-(4-methylphenyl)butyl hydroperoxide and tetraalkylammonium bromides (Alk4NBr) in CDCl3 was experimentally confirmed by NMR1H spectroscopy. Thermodynamic parameters for the hydroperoxide-Alk4NBr complexes were estimated. Effect of the Alk4N+ cation...

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Bibliographic Details
Published inJournal of characterization and development of novel materials Vol. 9; no. 4; pp. 263 - 269
Main Authors Berestneva, Yu V, Raksha, E V, Turovskij, N A, Zaikov, G E
Format Journal Article
LanguageEnglish
Published Hauppauge Nova Science Publishers, Inc 01.10.2017
Subjects
Bromides
Butyl hydroperoxide
Catalytic oxidation
Cations
Complex formation
Decomposition
Hydrocarbons
Investigations
Parameter estimation
Solvent effect
Spectrum analysis
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Summary:The formation of a complex between 1,1,3-trimethyl-3-(4-methylphenyl)butyl hydroperoxide and tetraalkylammonium bromides (Alk4NBr) in CDCl3 was experimentally confirmed by NMR1H spectroscopy. Thermodynamic parameters for the hydroperoxide-Alk4NBr complexes were estimated. Effect of the Alk4N+ cation on the complex parameters is discussed.
ISSN:1937-7975