Substitution reactions at the Ni(III) cation in macrobicyclic complexes - Reaction of metal ion complexes prepared from ligands L(1) (17-oxa-1,4,8,11-tetraazabicyclo[6.5.6]nonadecane)
The potentially penta-coordinating ligand L1 has been synthesized by reaction of the bridge bis-(2-methylsulfonyl)oxyethyl)ether with the tetraazamacrocycle cyclam. The detachment of the ether O donor to yield a square-planar complex is confirmed, and comparisons are made with substitution rates at...
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| Published in | Canadian journal of chemistry Vol. 80; no. 2; p. 155 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Ottawa
Canadian Science Publishing NRC Research Press
01.02.2002
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| Subjects | |
| Online Access | Get full text |
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| Abstract | The potentially penta-coordinating ligand L1 has been synthesized by reaction of the bridge bis-(2-methylsulfonyl)oxyethyl)ether with the tetraazamacrocycle cyclam. The detachment of the ether O donor to yield a square-planar complex is confirmed, and comparisons are made with substitution rates at other Ni(III) macrocyclic ions. |
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| AbstractList | The potentially penta-coordinating ligand L1 has been synthesized by reaction of the bridge bis-(2-methylsulfonyl)oxyethyl)ether with the tetraazamacrocycle cyclam. The detachment of the ether O donor to yield a square-planar complex is confirmed, and comparisons are made with substitution rates at other Ni(III) macrocyclic ions. |
| Author | Ingham, Alison M Xu, Chao Whitcombe, T W Xu, Chengtian |
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| Snippet | The potentially penta-coordinating ligand L1 has been synthesized by reaction of the bridge bis-(2-methylsulfonyl)oxyethyl)ether with the tetraazamacrocycle... |
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| Title | Substitution reactions at the Ni(III) cation in macrobicyclic complexes - Reaction of metal ion complexes prepared from ligands L(1) (17-oxa-1,4,8,11-tetraazabicyclo[6.5.6]nonadecane) |
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