Synthesis and characterization of titanium complexes containing phosphinimido and tropidinyl ligands: Crystal structure of (trop(t-Bu(3)PN)TiCl(2)
A new class of titanium complexes containing a tropidinyl (trop) ligand and a phosphinimido (R3P=N-) or a ketimide ligand (R2C=N-) were synthesized and characterized. The combination of the cyclopentadienyl equivalent tropidinyl and phosphinimido ligands enables the formation of a group of novel non...
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Published in | Canadian journal of chemistry Vol. 80; no. 11; p. 1618 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Ottawa
Canadian Science Publishing NRC Research Press
01.11.2002
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Subjects | |
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Abstract | A new class of titanium complexes containing a tropidinyl (trop) ligand and a phosphinimido (R3P=N-) or a ketimide ligand (R2C=N-) were synthesized and characterized. The combination of the cyclopentadienyl equivalent tropidinyl and phosphinimido ligands enables the formation of a group of novel non-metallocene catalysts for olefin polymerization. The crystal structure of (trop)(t-Bu3PN)TiCl2 was determined by single crystal X-ray crystallography. Polymerization of ethylene with this complex was studied in a high-temperature solution process. |
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AbstractList | A new class of titanium complexes containing a tropidinyl (trop) ligand and a phosphinimido (R3P=N-) or a ketimide ligand (R2C=N-) were synthesized and characterized. The combination of the cyclopentadienyl equivalent tropidinyl and phosphinimido ligands enables the formation of a group of novel non-metallocene catalysts for olefin polymerization. The crystal structure of (trop)(t-Bu3PN)TiCl2 was determined by single crystal X-ray crystallography. Polymerization of ethylene with this complex was studied in a high-temperature solution process. |
Author | Rupert E v H Spence Brown, Steve J Gao, Xiaoliang Kowalchuk, Matthew G |
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Copyright | Copyright National Research Council of Canada Nov 2002 |
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SubjectTerms | Chemical bonds Chemical structure Chemistry Crystallography Crystals High temperature Organometallic compounds Titanium Titanium compounds |
Title | Synthesis and characterization of titanium complexes containing phosphinimido and tropidinyl ligands: Crystal structure of (trop(t-Bu(3)PN)TiCl(2) |
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