[pi]-Conjugated Microporous Polymer Films: Designed Synthesis, Conducting Properties, and Photoenergy Conversions
Conjugated microporous polymers are a unique class of polymers that combine extended π-conjugation with inherent porosity. However, these polymers are synthesized through solution-phase reactions to yield insoluble and unprocessable solids, which preclude not only the evaluation of their conducting...
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Published in | Angewandte Chemie Vol. 127; no. 46; p. 13798 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | German |
Published |
Weinheim
Wiley Subscription Services, Inc
09.11.2015
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Abstract | Conjugated microporous polymers are a unique class of polymers that combine extended π-conjugation with inherent porosity. However, these polymers are synthesized through solution-phase reactions to yield insoluble and unprocessable solids, which preclude not only the evaluation of their conducting properties but also the fabrication of thin films for device implementation. Here, we report a strategy for the synthesis of thin films of π-conjugated microporous polymers by designing thiophene-based electropolymerization at the solution-electrode interface. High-quality films are prepared on a large area of various electrodes, the film thickness is controllable, and the films are used for device fabrication. These films are outstanding hole conductors and, upon incorporation of fullerenes into the pores, function as highly efficient photoactive layers for energy conversions. Our film strategy may boost the applications in photocatalysis, energy storage, and optoelectronics. |
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AbstractList | Conjugated microporous polymers are a unique class of polymers that combine extended π-conjugation with inherent porosity. However, these polymers are synthesized through solution-phase reactions to yield insoluble and unprocessable solids, which preclude not only the evaluation of their conducting properties but also the fabrication of thin films for device implementation. Here, we report a strategy for the synthesis of thin films of π-conjugated microporous polymers by designing thiophene-based electropolymerization at the solution-electrode interface. High-quality films are prepared on a large area of various electrodes, the film thickness is controllable, and the films are used for device fabrication. These films are outstanding hole conductors and, upon incorporation of fullerenes into the pores, function as highly efficient photoactive layers for energy conversions. Our film strategy may boost the applications in photocatalysis, energy storage, and optoelectronics. |
Author | Chen, Youchun Zhang, Shitong Ma, Yuguang Huang, Ning Gu, Cheng Qin, Leiqiang Li, Fenghong Xu, Hong Jiang, Donglin |
Author_xml | – sequence: 1 givenname: Cheng surname: Gu fullname: Gu, Cheng – sequence: 2 givenname: Ning surname: Huang fullname: Huang, Ning – sequence: 3 givenname: Youchun surname: Chen fullname: Chen, Youchun – sequence: 4 givenname: Leiqiang surname: Qin fullname: Qin, Leiqiang – sequence: 5 givenname: Hong surname: Xu fullname: Xu, Hong – sequence: 6 givenname: Shitong surname: Zhang fullname: Zhang, Shitong – sequence: 7 givenname: Fenghong surname: Li fullname: Li, Fenghong – sequence: 8 givenname: Yuguang surname: Ma fullname: Ma, Yuguang – sequence: 9 givenname: Donglin surname: Jiang fullname: Jiang, Donglin |
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Copyright | 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
Copyright_xml | – notice: 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
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SubjectTerms | Chemistry Design engineering Polymers Thin films |
Title | [pi]-Conjugated Microporous Polymer Films: Designed Synthesis, Conducting Properties, and Photoenergy Conversions |
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