CH Bond Activation by f-Block Complexes
Most homogeneous catalysis relies on the design of metal complexes to trap and convert substrates or small molecules to value-added products. Organometallic lanthanide compounds first gave a tantalizing glimpse of their potential for catalytic CH bond transformations with the selective cleavage of o...
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| Published in | Angewandte Chemie International Edition Vol. 54; no. 1; p. 82 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
Wiley Subscription Services, Inc
02.01.2015
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| Edition | International ed. in English |
| Online Access | Get full text |
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| Abstract | Most homogeneous catalysis relies on the design of metal complexes to trap and convert substrates or small molecules to value-added products. Organometallic lanthanide compounds first gave a tantalizing glimpse of their potential for catalytic CH bond transformations with the selective cleavage of one CH bond in methane by bis(permethylcyclopentadienyl)lanthanide methyl [(η5-C5Me5)2Ln(CH3)] complexes some 25years ago. Since then, numerous metal complexes from across the periodic table have been shown to selectively activate hydrocarbon CH bonds, but the challenges of closing catalytic cycles still remain; many f-block complexes show great potential in this important area of chemistry. |
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| AbstractList | Most homogeneous catalysis relies on the design of metal complexes to trap and convert substrates or small molecules to value-added products. Organometallic lanthanide compounds first gave a tantalizing glimpse of their potential for catalytic CH bond transformations with the selective cleavage of one CH bond in methane by bis(permethylcyclopentadienyl)lanthanide methyl [(η5-C5Me5)2Ln(CH3)] complexes some 25years ago. Since then, numerous metal complexes from across the periodic table have been shown to selectively activate hydrocarbon CH bonds, but the challenges of closing catalytic cycles still remain; many f-block complexes show great potential in this important area of chemistry. |
| Author | McMullon, Max W Arnold, Polly L Kuhn, Fritz E Rieb, Julia |
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| Copyright | 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
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| DOI | 10.1002/anie.201404613 |
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| Snippet | Most homogeneous catalysis relies on the design of metal complexes to trap and convert substrates or small molecules to value-added products. Organometallic... |
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| Title | CH Bond Activation by f-Block Complexes |
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