Pentadienyl-metal-phosphine chemistry. X: Comparison of the reactions of (n5-pentadienyl)Mn[(Me2PCH2)3CMe] and (n5-2,4-dimethylpentadienyl)Re(PMe2Ph)3 with H+. Isolation of a protonated manganese complex containing an agostic C-H-M interaction

• Published in: Journal of the American Chemical Society Vol. 109; no. 2; pp. 417 - 423
• Main Authors: BLEEKE, J. R, KOTYK, J. J, MOORE, D. A, RAUSCHER, D. J
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 1987
• Subjects: Chemistry; Condensed matter: structure, mechanical and thermal properties; Exact sciences and technology; Inorganic compounds; Metal complexes; Organic chemistry; Organometalloidal and organometallic compounds; Physics; Preparations and properties; Structure of solids and liquids; crystallography; Structure of specific crystalline solids; Transition metals derivatives; Cationic complex; Tertiary phosphine; Molecular structure; Organic ligand; Transition metal Complexes; Experimental study; X ray diffraction; Hydrido complex; Tritertiary phosphine; Hapto complex; Manganese Organic compounds; NMR spectrum; Rhenium Organic compounds; Crystalline structure