An in-depth analytical approach to the mechanism of the RAFT process in acrylate free radical polymerizations via coupled size exclusion chromatography-electrospray ionization mass spectrometry (SEC-ESI-MS) : Controlled macromolecular synthesis and controlled architectures: Supramolecular polymer assemblies
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| Published in | Polymer (Guildford) Vol. 46; no. 19; pp. 8448 - 8457 |
|---|---|
| Main Authors | , , , , |
| Format | Conference Proceeding |
| Language | English |
| Published |
Oxford
Elsevier
2005
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| Subjects | |
| Online Access | Get full text |
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| Author | BARNER-KOWOLLIK, Christopher DAVIS, Thomas P STENZEL, Martina H FELDERMANN, Achim AH TOY, Andrew |
|---|---|
| Author_xml | – sequence: 1 givenname: Achim surname: FELDERMANN fullname: FELDERMANN, Achim organization: School of Chemical Engineering and Industrial Chemistry, Centre for Advanced Macromolecular Design (CAMD), The University of New South Wales, Sydney, NSW 2052, Australia – sequence: 2 givenname: Andrew surname: AH TOY fullname: AH TOY, Andrew organization: School of Chemical Engineering and Industrial Chemistry, Centre for Advanced Macromolecular Design (CAMD), The University of New South Wales, Sydney, NSW 2052, Australia – sequence: 3 givenname: Thomas P surname: DAVIS fullname: DAVIS, Thomas P organization: School of Chemical Engineering and Industrial Chemistry, Centre for Advanced Macromolecular Design (CAMD), The University of New South Wales, Sydney, NSW 2052, Australia – sequence: 4 givenname: Martina H surname: STENZEL fullname: STENZEL, Martina H organization: School of Chemical Engineering and Industrial Chemistry, Centre for Advanced Macromolecular Design (CAMD), The University of New South Wales, Sydney, NSW 2052, Australia – sequence: 5 givenname: Christopher surname: BARNER-KOWOLLIK fullname: BARNER-KOWOLLIK, Christopher organization: School of Chemical Engineering and Industrial Chemistry, Centre for Advanced Macromolecular Design (CAMD), The University of New South Wales, Sydney, NSW 2052, Australia |
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| Keywords | Bulk polymerization Butyl acrylate polymer Coupled method Electrospray ionization mass spectrometry (ESI-MS) Dithioester Experimental study Methyl acrylate polymer Electrospray Gel permeation chromatography Free radical polymerization Chain transfer Investigation method Reaction mechanism Kinetics Mass spectrometer Mechanism and kinetics Reversible addition fragmentation chain transfer (RAFT) polymerization |
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| SubjectTerms | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts |
| Title | An in-depth analytical approach to the mechanism of the RAFT process in acrylate free radical polymerizations via coupled size exclusion chromatography-electrospray ionization mass spectrometry (SEC-ESI-MS) : Controlled macromolecular synthesis and controlled architectures: Supramolecular polymer assemblies |
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