Six-electron organic redoxmers for aqueous redox flow batteries

Here we have developed a novel molecular design that enables six-electron redox activity in fused phenazine-based organic scaffolds. Combined electrochemical and spectroscopic tests successfully confirm the two-step 6e- redox mechanism. This work offers an opportunity for achieving energy-dense redo...

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Published inChemical communications (Cambridge, England) Vol. 58; no. 95
Main Authors Fang, Xiaoting, Cavazos, Andres T., Li, Zhiguang, Li, Chenzhao, Xie, Jian, Wassall, Stephen R., Zhang, Lu, Wei, Xiaoliang
Format Journal Article
LanguageEnglish
Published United States Royal Society of Chemistry 07.11.2022
Subjects
ENERGY STORAGE
flow battery
multiple electron
redoxmer
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Abstract Here we have developed a novel molecular design that enables six-electron redox activity in fused phenazine-based organic scaffolds. Combined electrochemical and spectroscopic tests successfully confirm the two-step 6e- redox mechanism. This work offers an opportunity for achieving energy-dense redox flow batteries, on condition that the solubility and stability issues are addressed.
AbstractList Here we have developed a novel molecular design that enables six-electron redox activity in fused phenazine-based organic scaffolds. Combined electrochemical and spectroscopic tests successfully confirm the two-step 6e- redox mechanism. This work offers an opportunity for achieving energy-dense redox flow batteries, on condition that the solubility and stability issues are addressed.
Author Zhang, Lu
Li, Chenzhao
Xie, Jian
Fang, Xiaoting
Li, Zhiguang
Wei, Xiaoliang
Wassall, Stephen R.
Cavazos, Andres T.
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  fullname: Cavazos, Andres T.
  organization: Indiana University-Purdue University Indianapolis (IUPUI), Indianapolis, IN (United States)
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  fullname: Li, Zhiguang
  organization: Indiana University-Purdue University Indianapolis (IUPUI), Indianapolis, IN (United States); Purdue University, West Lafayette, IN (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
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  fullname: Li, Chenzhao
  organization: Indiana University-Purdue University Indianapolis (IUPUI), Indianapolis, IN (United States); Purdue University, West Lafayette, IN (United States)
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  fullname: Xie, Jian
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  fullname: Wassall, Stephen R.
  organization: Indiana University-Purdue University Indianapolis, 425 University Boulevard, Indianapolis, IN, 46202, USA
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  fullname: Zhang, Lu
  organization: Argonne National Laboratory (ANL), Argonne, IL (United States)] (ORCID:0000000303670862
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  fullname: Wei, Xiaoliang
  organization: Indiana University-Purdue University Indianapolis (IUPUI), Indianapolis, IN (United States)] (ORCID:0000000276922357
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Snippet Here we have developed a novel molecular design that enables six-electron redox activity in fused phenazine-based organic scaffolds. Combined electrochemical...
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SubjectTerms ENERGY STORAGE
flow battery
multiple electron
redoxmer
Title Six-electron organic redoxmers for aqueous redox flow batteries
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