Incremental Tuning Up of Fluorous Phenazine Acceptors
Abstract In a simple, one‐step direct trifluoromethylation of phenazine with CF 3 I we prepared and characterized nine (poly)trifluoromethyl derivatives with up to six CF 3 groups. The electrochemical reduction potentials and gas‐phase electron affinities show a direct, strict linear relation to the...
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| Published in | Chemistry : a European journal Vol. 22; no. 12 |
|---|---|
| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Wiley Blackwell (John Wiley & Sons)
12.01.2016
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| Online Access | Get full text |
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| Abstract | Abstract
In a simple, one‐step direct trifluoromethylation of phenazine with CF
3
I we prepared and characterized nine (poly)trifluoromethyl derivatives with up to six CF
3
groups. The electrochemical reduction potentials and gas‐phase electron affinities show a direct, strict linear relation to the number of CF
3
groups, with phenazine(CF
3
)
6
reaching a record‐high electron affinity of 3.24 eV among perfluoroalkylated polyaromatics. |
|---|---|
| AbstractList | Abstract
In a simple, one‐step direct trifluoromethylation of phenazine with CF
3
I we prepared and characterized nine (poly)trifluoromethyl derivatives with up to six CF
3
groups. The electrochemical reduction potentials and gas‐phase electron affinities show a direct, strict linear relation to the number of CF
3
groups, with phenazine(CF
3
)
6
reaching a record‐high electron affinity of 3.24 eV among perfluoroalkylated polyaromatics. |
| Author | Bukovsky, Eric V. Kuvychko, Igor V. Chen, Yu‐Sheng Rippy, Kerry C. Boltalina, Olga V. Wang, Xue‐Bin Hou, Gao‐Lei Strauss, Steven H. Castro, Karlee P. Clikeman, Tyler T. DeWeerd, Nicholas J. |
| Author_xml | – sequence: 1 fullname: Castro, Karlee P. organization: Department of Chemistry Colorado State University Fort Collins CO 80523 USA – sequence: 2 fullname: Clikeman, Tyler T. organization: Department of Chemistry Colorado State University Fort Collins CO 80523 USA – sequence: 3 fullname: DeWeerd, Nicholas J. organization: Department of Chemistry Colorado State University Fort Collins CO 80523 USA – sequence: 4 fullname: Bukovsky, Eric V. organization: Department of Chemistry Colorado State University Fort Collins CO 80523 USA – sequence: 5 fullname: Rippy, Kerry C. organization: Department of Chemistry Colorado State University Fort Collins CO 80523 USA – sequence: 6 fullname: Kuvychko, Igor V. organization: Department of Chemistry Colorado State University Fort Collins CO 80523 USA – sequence: 7 fullname: Hou, Gao‐Lei organization: Physical Sciences Division Pacific Northwest National Laboratory Richland WA 99352 USA – sequence: 8 fullname: Chen, Yu‐Sheng organization: ChemMatCARS University of Chicago, Advanced Photon Source Argonne IL 60439 USA – sequence: 9 fullname: Wang, Xue‐Bin organization: Physical Sciences Division Pacific Northwest National Laboratory Richland WA 99352 USA – sequence: 10 fullname: Strauss, Steven H. organization: Department of Chemistry Colorado State University Fort Collins CO 80523 USA – sequence: 11 fullname: Boltalina, Olga V. organization: Department of Chemistry Colorado State University Fort Collins CO 80523 USA |
| BackLink | https://www.osti.gov/biblio/1401639$$D View this record in Osti.gov |
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In a simple, one‐step direct trifluoromethylation of phenazine with CF
3
I we prepared and characterized nine (poly)trifluoromethyl derivatives with... |
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| Title | Incremental Tuning Up of Fluorous Phenazine Acceptors |
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