Pt and Pd catalyzed oxidation of Li2O2 and DMSO during Li–O2 battery charging

Rechargeable Li–O2 and Li–air batteries require electrode and electrolyte materials that synergistically promote long-term cell operation. In this study, we investigate the role of noble metals Pt and Pd as catalysts in the Li–O2 oxidation process and their compatibility with dimethyl sulfoxide (DMS...

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Published inChemical communications (Cambridge, England) Vol. 7; no. C
Main Authors Gittleson, Forrest S., Ryu, Won-Hee, Schwab, Mark, Tong, Xiao, Taylor, André D.
Format Journal Article
LanguageEnglish
Published United States 01.01.2016
Subjects
ENERGY STORAGE
MATERIALS SCIENCE
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Abstract Rechargeable Li–O2 and Li–air batteries require electrode and electrolyte materials that synergistically promote long-term cell operation. In this study, we investigate the role of noble metals Pt and Pd as catalysts in the Li–O2 oxidation process and their compatibility with dimethyl sulfoxide (DMSO) based electrolytes. Here, we identify a basis for low potential Li2O2 evolution followed by oxidative decomposition of the electrolyte to form carbonate side products.
AbstractList Rechargeable Li–O2 and Li–air batteries require electrode and electrolyte materials that synergistically promote long-term cell operation. In this study, we investigate the role of noble metals Pt and Pd as catalysts in the Li–O2 oxidation process and their compatibility with dimethyl sulfoxide (DMSO) based electrolytes. Here, we identify a basis for low potential Li2O2 evolution followed by oxidative decomposition of the electrolyte to form carbonate side products.
Author Gittleson, Forrest S.
Schwab, Mark
Taylor, André D.
Ryu, Won-Hee
Tong, Xiao
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  organization: Yale Univ., New Haven, CT (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
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  fullname: Ryu, Won-Hee
  organization: Yale Univ., New Haven, CT (United States); Sookmyung Women's Univ., Seoul (South Korea)
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  fullname: Schwab, Mark
  organization: Yale Univ., New Haven, CT (United States)
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  fullname: Tong, Xiao
  organization: Brookhaven National Lab. (BNL), Upton, NY (United States)
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  fullname: Taylor, André D.
  organization: Yale Univ., New Haven, CT (United States)
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Brookhaven National Lab. (BNL), Upton, NY (United States)
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USDOE Office of Science (SC), Basic Energy Sciences (BES)
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Snippet Rechargeable Li–O2 and Li–air batteries require electrode and electrolyte materials that synergistically promote long-term cell operation. In this study, we...
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Title Pt and Pd catalyzed oxidation of Li2O2 and DMSO during Li–O2 battery charging
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