컴팩트 개질기용 수성가스전이 반응을 위한 Cu-CeO 2 촉매에 대한 Nb 2 O 5 의 영향

The water-gas shift reaction for the compact reformer was carried out at a gas hourly space velocity of 72,152 h-1 over the Cu-Nb-CeO2 catalysts prepared by co-precipitation method. In order to investigate the effect of Nb2O5 promotion over a Cu-CeO2 catalyst, the Nb2O5 loading amount was systematic...

Full description

Saved in:
Bibliographic Details
Published in한국수소 및 신에너지학회 논문집 Vol. 31; no. 1; pp. 57 - 64
Main Authors 정창훈, 김태광, 변희주, 김주환, 배은택, 선해림, 전경원, 정대운, JEONG, CHANG-HOON, KIM, TAE-GWANG, BYON, HUI-JU, KIM, JU-HWAN, BAE, EUN-TAEK, SHEN, KAILIN, JEON, KYUNG-WON, JEONG, DAE-WOON
Format Journal Article
LanguageKorean
Published 2020
Subjects
Nb_2O_5
Online AccessGet full text

Cover

Abstract The water-gas shift reaction for the compact reformer was carried out at a gas hourly space velocity of 72,152 h-1 over the Cu-Nb-CeO2 catalysts prepared by co-precipitation method. In order to investigate the effect of Nb2O5 promotion over a Cu-CeO2 catalyst, the Nb2O5 loading amount was systematically changed from 0 to 5 wt.%. Among the prepared catalysts, the Cu-Nb-CeO2 (1%) catalyst showed the highest catalytic activity (CO conversion=61% at 400℃) as well as 100% CO2 selectivity. The high activity and stability of Cu-Nb-CeO2 (1%) catalyst are correlated to high Brunauer-Emmett-Teller surface area, small metallic Cu crystallite size, and enhanced redox property.
AbstractList The water-gas shift reaction for the compact reformer was carried out at a gas hourly space velocity of 72,152 h-1 over the Cu-Nb-CeO2 catalysts prepared by co-precipitation method. In order to investigate the effect of Nb2O5 promotion over a Cu-CeO2 catalyst, the Nb2O5 loading amount was systematically changed from 0 to 5 wt.%. Among the prepared catalysts, the Cu-Nb-CeO2 (1%) catalyst showed the highest catalytic activity (CO conversion=61% at 400℃) as well as 100% CO2 selectivity. The high activity and stability of Cu-Nb-CeO2 (1%) catalyst are correlated to high Brunauer-Emmett-Teller surface area, small metallic Cu crystallite size, and enhanced redox property.
Author JEON, KYUNG-WON
선해림
JEONG, CHANG-HOON
정창훈
정대운
KIM, JU-HWAN
SHEN, KAILIN
BAE, EUN-TAEK
변희주
전경원
배은택
JEONG, DAE-WOON
김주환
BYON, HUI-JU
김태광
KIM, TAE-GWANG
Author_xml – sequence: 1
  fullname: 정창훈
– sequence: 2
  fullname: 김태광
– sequence: 3
  fullname: 변희주
– sequence: 4
  fullname: 김주환
– sequence: 5
  fullname: 배은택
– sequence: 6
  fullname: 선해림
– sequence: 7
  fullname: 전경원
– sequence: 8
  fullname: 정대운
– sequence: 9
  fullname: JEONG, CHANG-HOON
– sequence: 10
  fullname: KIM, TAE-GWANG
– sequence: 11
  fullname: BYON, HUI-JU
– sequence: 12
  fullname: KIM, JU-HWAN
– sequence: 13
  fullname: BAE, EUN-TAEK
– sequence: 14
  fullname: SHEN, KAILIN
– sequence: 15
  fullname: JEON, KYUNG-WON
– sequence: 16
  fullname: JEONG, DAE-WOON
BookMark eNrjYmDJy89LZWHgNDQ3ttA1NzIz4WDgLS7OTDIwMDQ0NTQzN-NkyHize8vbnpVvu3YovNow583yjlc7NryZtVLhTceMNy0bX21oeNO15M2Cljdztyi83jDjzdyJb-a2KLyZ0_J26hwF51Jd51R_BSOFN1s6Xy9f8mb6BIXXPQ0gGb8koKi_gqnCm7kzFN7MaHw7bSkPA2taYk5xKi-U5mZQdXMNcfbQzc4sLsmMz0spzon3cvT2NzIwMjA0NjEzNLG0sDQyMSZWHQC6l14F
ContentType Journal Article
DBID JDI
DEWEY 621.042
DatabaseName KoreaScience
DatabaseTitleList
DeliveryMethod fulltext_linktorsrc
EndPage 64
ExternalDocumentID JAKO202013461498924
GroupedDBID .UV
ALMA_UNASSIGNED_HOLDINGS
JDI
ID FETCH-kisti_ndsl_JAKO2020134614989243
ISSN 1738-7264
IngestDate Fri Dec 22 11:58:26 EST 2023
IsOpenAccess true
IsPeerReviewed false
IsScholarly false
Issue 1
Keywords Nb_2O_5
Language Korean
LinkModel OpenURL
MergedId FETCHMERGED-kisti_ndsl_JAKO2020134614989243
Notes KISTI1.1003/JNL.JAKO202013461498924
OpenAccessLink http://click.ndsl.kr/servlet/LinkingDetailView?cn=JAKO202013461498924&dbt=JAKO&org_code=O481&site_code=SS1481&service_code=01
ParticipantIDs kisti_ndsl_JAKO202013461498924
PublicationCentury 2000
PublicationDate 2020
PublicationDateYYYYMMDD 2020-01-01
PublicationDate_xml – year: 2020
  text: 2020
PublicationDecade 2020
PublicationTitle 한국수소 및 신에너지학회 논문집
PublicationTitleAlternate Transactions of the Korean Hydrogen and New Energy Society
PublicationYear 2020
SSID ssib001151676
ssib044738289
ssib053377300
ssib008451833
ssib012146272
Score 3.4677434
Snippet The water-gas shift reaction for the compact reformer was carried out at a gas hourly space velocity of 72,152 h-1 over the Cu-Nb-CeO2 catalysts prepared by...
SourceID kisti
SourceType Open Access Repository
StartPage 57
Title 컴팩트 개질기용 수성가스전이 반응을 위한 Cu-CeO 2 촉매에 대한 Nb 2 O 5 의 영향
URI http://click.ndsl.kr/servlet/LinkingDetailView?cn=JAKO202013461498924&dbt=JAKO&org_code=O481&site_code=SS1481&service_code=01
Volume 31
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnR1NaxNBdKk9eRFFxc8yB-cUIvsxsztz3N2klEqTS4Xeym52g6K0oOnFQ6mQQy096EENkoCHSuktQg4F_1Ey-Q---dhkI8Gvy-bx5n2_Xea9ITNjWY_8nFO37WbQlmReleR-Wk08n1RbgZdkScsFLrk0sNXwN56SzR26s3LlsLy7pJM-br1Zuq_kf7IKOMir3CX7D5mdCQUEwJBfeEKG4flXOcb1GEcRjgiu1zCLccgVEOKIVXAdfmzMY0kUBpgxhWESCRgeAnVFQjDAmQIIjhzDxhQRSAqJ4rflqGSrgTZgi5RsZlDcMQAjSiRXwsAUTgGuxAfVOG9WXDUGxjIuBYBNWjgPMLeVTHBBKi74GinwNCu0UqhhGmJQ_ioqH4e0XF3PWJUXFIe1RQd90FAYz9a195F0rrBCGUFUrHTQZtaoyELQjABGcRQrL2IZU03NZ6-viRkwSo9tHNUUO_CxOQmYyI0G5hVGkwUpYKlXGFGTuqRcD0fxEilmRNFyrC_dLtZzXLs0-QQw-QSuPtW9mJ3MHFn-CvVUo8_1NkWL4Vk4TvyXaX7258vN8ElTKnY8ArUZZ9CBy8MfbE9eALJ1WJ9X01AN-qVqlRHqsHl34Mg74d35tmtCwH53fnkBNBKBvA1BbUk2nkELKPui56Uabvu6dc00XyjUX9INa-XF_k3rmfgxmp5eTE8u0XjYF-fH48uh-HKBxHFPdL-Ph0fi5Ex87YrBCE2GPTH4IAZdJPrd6cc-0m82cpEYvZucn4nP79Hk9EiONFLANhFFYtBDovd2-unbLQuv17fjjaqybXcve_1yd0mUvNvW6t7-Xn7HQm2SUUqzwHeclOTcTnOnnSZ24rWD3MmC5K619ntZ9_5EcN-6KjF6te-Btdp5dZA_hPq3k66pLP0EpB2Gfw
link.rule.ids 230,315,783,787,888,4032
linkProvider ISSN International Centre
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=%EC%BB%B4%ED%8C%A9%ED%8A%B8+%EA%B0%9C%EC%A7%88%EA%B8%B0%EC%9A%A9+%EC%88%98%EC%84%B1%EA%B0%80%EC%8A%A4%EC%A0%84%EC%9D%B4+%EB%B0%98%EC%9D%91%EC%9D%84+%EC%9C%84%ED%95%9C+Cu-CeO+2+%EC%B4%89%EB%A7%A4%EC%97%90+%EB%8C%80%ED%95%9C+Nb+2+O+5+%EC%9D%98+%EC%98%81%ED%96%A5&rft.jtitle=%ED%95%9C%EA%B5%AD%EC%88%98%EC%86%8C+%EB%B0%8F+%EC%8B%A0%EC%97%90%EB%84%88%EC%A7%80%ED%95%99%ED%9A%8C+%EB%85%BC%EB%AC%B8%EC%A7%91&rft.au=%EC%A0%95%EC%B0%BD%ED%9B%88&rft.au=%EA%B9%80%ED%83%9C%EA%B4%91&rft.au=%EB%B3%80%ED%9D%AC%EC%A3%BC&rft.au=%EA%B9%80%EC%A3%BC%ED%99%98&rft.date=2020&rft.issn=1738-7264&rft.volume=31&rft.issue=1&rft.spage=57&rft.epage=64&rft.externalDBID=n%2Fa&rft.externalDocID=JAKO202013461498924
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1738-7264&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1738-7264&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1738-7264&client=summon