Rotation dynamics of [C.sub.60] molecules in a monolayer fullerene film on the W[O.sub.2] /W

The rotation dynamics of [C.sub.60] molecules in monolayer fullerene films grown on the [WO.sub.2]/W(110) surface is studied by scanning tunneling microscopy. The formation of molecule clusters, which have a high libron vibration amplitude, is detected near the rotational phase transition temperatur...

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Published inJournal of experimental and theoretical physics Vol. 120; no. 5; pp. 831 - 1661
Main Authors Bozhko, S.I, Levchenko, E.A, Semenov, V.N, Bulatov, M.F, Shvets, I.V
Format Journal Article
LanguageEnglish
Published Springer 01.05.2015
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Abstract The rotation dynamics of [C.sub.60] molecules in monolayer fullerene films grown on the [WO.sub.2]/W(110) surface is studied by scanning tunneling microscopy. The formation of molecule clusters, which have a high libron vibration amplitude, is detected near the rotational phase transition temperature. The energy parameters that determine a change in the molecule orientation, namely, the energy difference between the nearest minima of the [C.sub.60] molecule energy (30 meV) as a function of the molecule orientation and the potential barrier between them (610 meV), are determined. The results are discussed in terms of the mean-field approximation.
AbstractList The rotation dynamics of [C.sub.60] molecules in monolayer fullerene films grown on the [WO.sub.2]/W(110) surface is studied by scanning tunneling microscopy. The formation of molecule clusters, which have a high libron vibration amplitude, is detected near the rotational phase transition temperature. The energy parameters that determine a change in the molecule orientation, namely, the energy difference between the nearest minima of the [C.sub.60] molecule energy (30 meV) as a function of the molecule orientation and the potential barrier between them (610 meV), are determined. The results are discussed in terms of the mean-field approximation.
Audience Academic
Author Levchenko, E.A
Bulatov, M.F
Semenov, V.N
Shvets, I.V
Bozhko, S.I
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  fullname: Shvets, I.V
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Title Rotation dynamics of [C.sub.60] molecules in a monolayer fullerene film on the W[O.sub.2] /W
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