Simulated moving bed systems for separation of para-xylene and processes for determining pump-around profiles of the simulated moving bed systems

• Main Authors: RAUCH ANDREA L, MURRAY RICHARD C
• Format: Patent
• Language: English
• Published: 11.11.2014
• Subjects: ACYCLIC OR CARBOCYCLIC COMPOUNDS; CHEMISTRY; COLORIMETRY; INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIRCHEMICAL OR PHYSICAL PROPERTIES; MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT,POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRA-RED,VISIBLE OR ULTRA-VIOLET LIGHT; MEASURING; METALLURGY; ORGANIC CHEMISTRY; PHYSICS; RADIATION PYROMETRY; TESTING

Embodiments of simulated moving bed systems for separating a preferentially adsorbed component from a feed stream and processes for determining a pump-around profile of the simulated moving bed systems are provided. The process comprises the steps of rotating a rotary valve to a first valve position to direct the feed stream to a first adsorbent sub-bed. An intermediate stream between two adsorbent sub-beds in direct fluid communication with each other is irradiated with laser light that is directed from a probe of a Raman system positioned for inline sampling of the intermediate stream. Scattered light from the irradiated intermediate stream is collected with the probe. A spectrum of the scattered light is generated with the Raman system to determine concentrations of the preferentially adsorbed component and one or more other components in the intermediate stream.