SILOXANE-BASED GEL ADHESIVES AND ARTICLES

• Main Authors: Sherman, Audrey A, Liu, Junkang J, Schuell, Christoph T.R, Welke, Siegfried K
• Format: Patent
• Language: English
• Published: 17.02.2022
• Subjects: ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; ADHESIVES; CHEMISTRY; COMPOSITIONS BASED THEREON; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS; DYES; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; NATURAL RESINS; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ORGANIC MACROMOLECULAR COMPOUNDS; PAINTS; POLISHES; THEIR PREPARATION OR CHEMICAL WORKING-UP; USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS; USE OF MATERIALS AS ADHESIVES

Siloxane-based gel adhesives with improved shear holding power are prepared from curable compositions. The curable compositions include a siloxane fluid with a viscosity of at least 1,000,000 centiPoise, a siloxane-(meth)acrylate co-polymer, and siloxane tackifying resin. The curable compositions can contain an initiator or can be cured by e-beam radiation without an initiator. The siloxane-(meth)acrylate copolymer is the reaction product of a reaction mixture of an ethylenically unsaturated siloxane-containing macromer, an alkyl (meth)acrylate monomer; optionally a reinforcing monomer, and an initiator.