ANION EXCHANGE MEMBRANE FOR ELECTRODIALYSIS APPLICATIONS AND PROCESS FOR THE PREPARATION THEREOF
The present invention relates to the preparation of novel anion exchange membranes from bicomponent or tricomponent copolymers containing both quaternizable and cross-linkable moieties. The bicomponent copolymers consisted with polyacrylonitrile and poly(2-dimethylaminoethyl) methacrylate and the tr...
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Format | Patent |
Language | English |
Published |
23.06.2016
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Abstract | The present invention relates to the preparation of novel anion exchange membranes from bicomponent or tricomponent copolymers containing both quaternizable and cross-linkable moieties. The bicomponent copolymers consisted with polyacrylonitrile and poly(2-dimethylaminoethyl) methacrylate and the tricomponent copolymers consisted with polyacryloniterle and poly2-dimethylaminoethyl) methacrylate and polyn-butyl acrylate. Quaternization of dimethyl amino groups of copolymer by methyl iodide followed by cross-linking of acrylonitrile groups of copolymer by hydrazine hydrate resulted anion exchange membrane with desired properties such as high ion exchange capacity (1.30-1.50 meqg−1), high transport number (0.92-0.93) for direct use in electrodyalysis unit. The tricomponent anion exchange membrane containing 32 wt % PDMA, 17 wt % PnBA, and 51 wt % PAN exhibited improved performance mainly in terms of low power consumption and high current efficiency during desalination of water. |
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AbstractList | The present invention relates to the preparation of novel anion exchange membranes from bicomponent or tricomponent copolymers containing both quaternizable and cross-linkable moieties. The bicomponent copolymers consisted with polyacrylonitrile and poly(2-dimethylaminoethyl) methacrylate and the tricomponent copolymers consisted with polyacryloniterle and poly2-dimethylaminoethyl) methacrylate and polyn-butyl acrylate. Quaternization of dimethyl amino groups of copolymer by methyl iodide followed by cross-linking of acrylonitrile groups of copolymer by hydrazine hydrate resulted anion exchange membrane with desired properties such as high ion exchange capacity (1.30-1.50 meqg−1), high transport number (0.92-0.93) for direct use in electrodyalysis unit. The tricomponent anion exchange membrane containing 32 wt % PDMA, 17 wt % PnBA, and 51 wt % PAN exhibited improved performance mainly in terms of low power consumption and high current efficiency during desalination of water. |
Author | THAMPY SREEKUMARAN CHATTERJEE UMA JEWRAJKA SURESH KUMAR |
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Snippet | The present invention relates to the preparation of novel anion exchange membranes from bicomponent or tricomponent copolymers containing both quaternizable... |
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SubjectTerms | AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G CHEMISTRY COMPOSITIONS BASED THEREON GENERAL PROCESSES OF COMPOUNDING METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL SEPARATION THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE WORKING-UP |
Title | ANION EXCHANGE MEMBRANE FOR ELECTRODIALYSIS APPLICATIONS AND PROCESS FOR THE PREPARATION THEREOF |
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