Black trisazo metal complex dyes

• Main Authors: GEISENBERGER JOSEF, WUZIK ANDREAS
• Format: Patent
• Language: English
• Published: 11.10.2001
• Edition: 7
• Subjects: ADHESIVES; CHEMICAL PAINT OR INK REMOVERS; CHEMISTRY; CINEMATOGRAPHY; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS; COLOUR PRINTING; CORRECTING FLUIDS; DYEING LEATHER, FURS, OR SOLID MACROMOLECULAR SUBSTANCES INANY FORM; DYEING OR PRINTING TEXTILES; DYES; ELECTROGRAPHY; ELECTROPHOTOGRAPHY; FILLING PASTES; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR; HOLOGRAPHY; IMPREGNATING OR COATING OF PAPER; INKS; LAKES; LAUNDERING; LINING MACHINES; MAGNETOGRAPHY; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; MORDANTS; NATURAL RESINS; ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES; PAINTS; PAPER NOT OTHERWISE PROVIDED FOR; PAPER-MAKING; PASTES OR SOLIDS FOR COLOURING OR PRINTING; PERFORMING OPERATIONS; PHOTOGRAPHY; PHYSICS; POLISHES; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; PRINTING; PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; PRODUCTION OF CELLULOSE; PULP COMPOSITIONS; STAMPS; TEXTILES; TRANSPORTING; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; TREATMENT OF TEXTILES OR THE LIKE; TYPEWRITERS; USE OF MATERIALS THEREFOR; WOODSTAINS

Disclosed are metal complexes of trisazo dyes of the general formula 4 where R1 is aryl substituted by one or more, eg. 2, 3, 4 or 5, substituents selected from the group consisting of OH, O(C1-C6)-alkyl, O(C1-C6)-alkyl-COOM, O(C1-C6)-alkyl-SO3M, O(hydroxy(C1-C6)-alkyl), (C1-C6)-alkyl, COOM, SO3M, SO2NH2, SO2N(hydroxy(C1-C6)-alkyl)2, SO2NH(C1-C6)-alkyl, SO2N((C1-C6)-alkyl)2, NH2, NH(C1-C6)-alkyl, NHacyl, NHaryl, N(hydroxy(C1-C6)-alkyl)2, N((C1-C6)-alkyl)2 and halogen; R2 is OH, O(C1-C6)alkyl, COOM or SO3M; R3, R4 and R5 are each hydrogen or a substituent; R6 is a mono- or bicyclic carbocyclic or heterocyclic aromatic which is unsubstituted or substituted by one or more substituents, or is a similarly substituted pyrazole or pyridone radical. The dyes are useful for dyeing and printing natural and synthetic fiber materials, recording fluids, especially for the inkjet process, liquid formulations for paper pulp dyeing, and also as colorants for electrophotographic toners, powder coatings and color filters including the dyes of the invention.