Radiation-curable composition containing mercapto-functional polyorganosiloxanes for additive-manufacturing technology

• Main Authors: Osswald, Peter U, Hoffmann, Henning
• Format: Patent
• Language: English
• Published: 27.08.2024
• Subjects: ADDITIVE MANUFACTURING TECHNOLOGY; ADDITIVE MANUFACTURING, i.e. MANUFACTURING OFTHREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVEAGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING,STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING; CHEMISTRY; COMPOSITIONS BASED THEREON; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS; INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULARARTICLES; INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; PERFORMING OPERATIONS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR; SHAPING OR JOINING OF PLASTICS; THEIR PREPARATION OR CHEMICAL WORKING-UP; TRANSPORTING; WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL

The invention relates to a radiation-curable silicone composition for additive-manufacturing technology comprising mercapto-functional polyorganosiloxane(s) as Component A, organosiloxane(s) with at least two aliphatic unsaturated carbon-carbon moieties as Component B, photo-initiator(s) as Component C for initiating a curing reaction between Component A and Component B, dye(s) as Component D dissolved in mercapto-functional polyorganosiloxane(s) as Component E, the mercapto-functional polyorganosiloxane(s) having a fraction of (mercaptoalkyl)methylsiloxane units of at least 50 mol %, wherein Component D is dissolved in Component E before Component D is combined with the other components of the radiation-curable silicone composition. The invention also relates to a process of producing a radiation-curable composition wherein the process comprises the steps of providing a solution of dye(s) in a composition comprising mercapto-functional polyorganosiloxane(s) having a fraction of (mercaptoalkyl)methylsiloxane units of at least 50 mol %, combining the solution containing the dye(s) dissolved in the mercapto-functional polyorganosiloxane(s) with mercapto-functional polyorganosiloxane(s), organosiloxane(s) with at least two aliphatic unsaturated carbon-carbon moieties, photo-initiator(s) for initiating a curing reaction between Component A and Component B, optionally filler(s), stabilizer(s) and additive(s).