TRITIUM LABELED N-PHENYLQUINOLINIUM AND QUINALDINIUM SALTS AND METHOD FOR THEIR PREPARING

FIELD: organic chemistry, chemical technology. ^ SUBSTANCE: invention describes tritium labeled N-phenylquinolinium and quinaldinium salts of the general formula: wherein R means hydrogen atom (H), -CH3; X means BF- 4, ClO- 4, J-. Method involves ion-molecular reaction of quinoline or quinaldine (2-...

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Main Authors SHCHEPINA NADEZHDA EVGEN'EVNA, BADUN GENNADIJ ALEKSANDROVICH, AVRORIN VIKTOR VALENTINOVICH, ALEKSANDROVA GALINA ARSENT'EVNA
Format Patent
LanguageEnglish
Russian
Published 27.03.2008
Subjects
CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
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Summary:FIELD: organic chemistry, chemical technology. ^ SUBSTANCE: invention describes tritium labeled N-phenylquinolinium and quinaldinium salts of the general formula: wherein R means hydrogen atom (H), -CH3; X means BF- 4, ClO- 4, J-. Method involves ion-molecular reaction of quinoline or quinaldine (2-methylquinoline) with free tritium labeled phenyl cations that are generated spontaneously in beta-decay of tritium as components of tritium labeled benzene in a closed system in the presence of tetrafluoroborate, perchlorate or potassium iodide as a stabilizing salt. Novel substances can be used in biological and medicinal investigations. ^ EFFECT: improved method of synthesis. ^ 2 cl, 2 ex
Bibliography:Application Number: RU20060145294