POLYOLEFIN MICROPOROUS MEMBRANE

An objective of the present invention is to provide a polyolefin microporous membrane, a separator for an electrochemical device comprising the corresponding polyolefin microporous membrane, and an electrochemical device using the separator for the corresponding electrochemical device, which may inc...

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Main Authors SEKIGUCHI MANABU, KATAYAMA MASAKI
Format Patent
LanguageEnglish
Korean
Published 05.06.2020
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Abstract An objective of the present invention is to provide a polyolefin microporous membrane, a separator for an electrochemical device comprising the corresponding polyolefin microporous membrane, and an electrochemical device using the separator for the corresponding electrochemical device, which may increase an ion diffusion rate in electrolyte when using a separator for lithium ion secondary batteries and other electrochemical devices, may maintain an energy capacity during storage for a long period of time, may show excellent cycle characteristics and output characteristics even in an environment with a high temperature near a melting point, and may secure safety by blocking an ion permeation path through shutdown while maintaining insulation even in a temperature area exceeding the melting point. According to the present invention, a Li ion diffusion coefficient D (Z) of the polyolefin microporous membrane in a thickness direction thereof is 5.0 × 10^-11 m^2/s or more and 15.0 × 10^-11 m^2/s or less, a shutdown temperature is 150°C or lower, and a content of inorganic particles is 5 m% or more and less than 20 m%. [과제] 본 발명은, 리튬 이온 이차 전지 및 그 밖의 전기 화학 디바이스용 세퍼레이터로 했을 때 전해액 중에서의 이온 확산 속도를 높이고, 장기 보관했을 때 에너지 용량을 유지하고, 융점 부근의 고온 환경 하에서도 사이클 특성 및 출력 특성이 우수하고, 또한 융점을 초과한 온도 영역에 있어서도 절연을 유지하면서 셧 다운함으로써 이온의 투과 경로를 폐색해서 안전성을 담보할 수 있는, 폴리올레핀 미다공막, 해당 폴리올레핀 미다공막을 포함하는 전기 화학 디바이스용 세퍼레이터 및 해당 전기 화학 디바이스용 세퍼레이터를 사용한 전기 화학 디바이스를 제공하는 것을 목적으로 한다. [해결수단] 폴리올레핀 미다공막의 막 두께 방향의 Li 이온 확산 계수 D(Z)가, 5.0×10㎡/s 이상 15.0×10㎡/s 이하이고, 셧 다운 온도가 150℃ 이하이고, 또한 무기 입자의 함유량이 5질량% 이상 20질량% 미만이다.
AbstractList An objective of the present invention is to provide a polyolefin microporous membrane, a separator for an electrochemical device comprising the corresponding polyolefin microporous membrane, and an electrochemical device using the separator for the corresponding electrochemical device, which may increase an ion diffusion rate in electrolyte when using a separator for lithium ion secondary batteries and other electrochemical devices, may maintain an energy capacity during storage for a long period of time, may show excellent cycle characteristics and output characteristics even in an environment with a high temperature near a melting point, and may secure safety by blocking an ion permeation path through shutdown while maintaining insulation even in a temperature area exceeding the melting point. According to the present invention, a Li ion diffusion coefficient D (Z) of the polyolefin microporous membrane in a thickness direction thereof is 5.0 × 10^-11 m^2/s or more and 15.0 × 10^-11 m^2/s or less, a shutdown temperature is 150°C or lower, and a content of inorganic particles is 5 m% or more and less than 20 m%. [과제] 본 발명은, 리튬 이온 이차 전지 및 그 밖의 전기 화학 디바이스용 세퍼레이터로 했을 때 전해액 중에서의 이온 확산 속도를 높이고, 장기 보관했을 때 에너지 용량을 유지하고, 융점 부근의 고온 환경 하에서도 사이클 특성 및 출력 특성이 우수하고, 또한 융점을 초과한 온도 영역에 있어서도 절연을 유지하면서 셧 다운함으로써 이온의 투과 경로를 폐색해서 안전성을 담보할 수 있는, 폴리올레핀 미다공막, 해당 폴리올레핀 미다공막을 포함하는 전기 화학 디바이스용 세퍼레이터 및 해당 전기 화학 디바이스용 세퍼레이터를 사용한 전기 화학 디바이스를 제공하는 것을 목적으로 한다. [해결수단] 폴리올레핀 미다공막의 막 두께 방향의 Li 이온 확산 계수 D(Z)가, 5.0×10㎡/s 이상 15.0×10㎡/s 이하이고, 셧 다운 온도가 150℃ 이하이고, 또한 무기 입자의 함유량이 5질량% 이상 20질량% 미만이다.
Author KATAYAMA MASAKI
SEKIGUCHI MANABU
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Snippet An objective of the present invention is to provide a polyolefin microporous membrane, a separator for an electrochemical device comprising the corresponding...
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SubjectTerms AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G
BASIC ELECTRIC ELEMENTS
CAPACITORS
CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES ORLIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
CHEMISTRY
COMPOSITIONS BASED THEREON
ELECTRICITY
GENERAL PROCESSES OF COMPOUNDING
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES ASCOMPOUNDING INGREDIENTS
WORKING-UP
Title POLYOLEFIN MICROPOROUS MEMBRANE
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