PROCEDIMIENTO DE PREPARACION DE COMPUESTOS FUNGICIDAS AZOLIL-DERIVADOS

• Main Authors: GOZZO, FRANCO DR, CORDA, FRANCESCO, GARAVAGLIA, CARLO, MIRENNA, LUIGI, COLLE, ROBERTO DR, CAMAGGI, GIOVANNI DR
• Format: Patent
• Language: Spanish
• Published: 16.07.1992
• Edition: 5
• Subjects: ACYCLIC OR CARBOCYCLIC COMPOUNDS; AGRICULTURE; ANIMAL HUSBANDRY; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES; CHEMISTRY; FISHING; FORESTRY; HETEROCYCLIC COMPOUNDS; HUMAN NECESSITIES; HUNTING; METALLURGY; ORGANIC CHEMISTRY; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS; PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF; TRAPPING

SE PRESENTAN COMPUESTOS DE FORMULA GENERAL (I) ASI COMO LAS CORRESPONDIENTES SALES O COMPLEJOS METALICOS, DONDE: M=0,1; N=0,1; Z=CH, N; R1 SE SELECCIONA ENTRE CLORO, BROMO, FLUOR, CF3, FENILO, ALCOXI C1-C2, HALOALCOXI C1-C2, TIOALQUILO O HALOTIOALQUILO SIENDO EL HALOGENO CL, BR O F; R2 ES H, FLUOR, CLORO O BROMO; R3 REPRESENTA H, CH3, CN, O TAMBIEN F CUANDO M=1 O CUANDO N=1 Y R4 Y R5 SON H; R4 Y R5 SON, INDEPENDIENTEMENTE H O F; R3 Y R4, CUANDO M=C PUEDEN ADEMAS REPRESENTAR, EN CONJUNTO, UN SEGUNDO ENLACE ENTRE LOS DOS ATOMOS DE CARBONO A LOS QUE ESTAN LIGADOS EN LA FORMULA (I); RF SE SELECCIONA ENTRE EL GRUPO FORMADO POR POLIFLUORALQUILOS, POLIFLUORALQUENILOS Y POLIFLUORALQUINILOS QUE CONTIENEN HASTA 4 ATOMOS DE CARBONO, CONTENIENDO AL MENOS DOS ATOMOS DE F Y, OPCIONALMENTE, OTROS HALOGENOS SELECCIONADOS ENTRE CL Y BR. Disclosed are compounds, having the general formula: as well as corresponding salts or metal complexes, wherein:m = 0, 1; n = 0, 1;Z = CH, N;R₁ is selected from chlorine, bromine, fluorine, CF₃, phe­nyl, C₁-C₂-alkoxy, C₁-C₂-haloalkoxy, alkylthio, haloalkylthiowherein the halogen is Cl, Br, F;R₂ is H, fluorine, chlorine, bromine;R₃ represents H, CH₃, CN, or also F when m = 1 or when n = 1 and R₄, R₅ are H;R₄, R₅ are independently H or F;R₃ and R₄, when m= C, can furthermore represent, taken together, a second bond between the two carbon atoms to which they are linked in formula (I);Rf is selected from the group formed by polyfluoroalkyls, polyfluoroalkenyls and polyfluoroalkynyls containing up to 4 carbon atoms, containing at least 2 F atoms and, optionally, other halogens selected from Cl and Br.