HYDROCARBON MIXTURE EXHIBITING UNIQUE BRANCHING STRUCTURE

• Main Authors: THOMAS, Benton, HAO, Yalin, WELLS, Jason, BARALT, Eduardo, ROSALLI, Jason, HO, Liwenny, HO, Willbe, CHEN, Cong, Yan, PRADHAN, Ajit
• Format: Patent
• Language: English; French; German
• Published: 27.09.2023
• Subjects: CHEMISTRY; CRACKING HYDROCARBON OILS; FUELS; INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATINGCOMPOSITIONS; LUBRICANTS; LUBRICATING COMPOSITIONS; METALLURGY; MINERAL WAXES; PEAT; PETROLEUM, GAS OR COKE INDUSTRIES; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; TECHNICAL GASES CONTAINING CARBON MONOXIDE; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATINGINGREDIENTS IN A LUBRICATING COMPOSITION

Provided herein are hydrocarbon mixtures with controlled structure characteristics that address the performance requirements for finished lubricants driven by the stricter environmental and fuel economy regulations. The branching characteristics of the hydrocarbon molecules are controlled to provide a composition that has a unique and superior viscosity-temperature relationship and Noack volatility. An important aspect of the present invention relates to a saturated hydrocarbon mixture with at least 80% of the molecules having an even carbon number, with the branching characteristic of BP/BI in the range≥−0.6037 (Internal alkyl branching)+2.0, where on average at least 0.3 to 1.5 of the internal methyl branches are located more than 4 carbons away from the terminal carbon when analyzed by carbon NMR. The saturated hydrocarbon mixture with such unique branching structure consistently exhibits a stand out performance in the cold crank simulated viscosity (CCS) vs Noack volatility relationship, which allows for the formulation of lower viscosity engine oils with improved fuel economies.