Process for preparing aryl allyl ethers
A process for preparing an aryl allyl ether is disclosed comprising reacting (a) a phenolic compound with (b) an allyl acetate in the presence of (c) an allylation catalyst selected from a ruthenium or rare earth metal catalyst complex comprising at least one stable ligand containing a substituted a...
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Format | Patent |
Language | English French German |
Published |
23.05.2007
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Abstract | A process for preparing an aryl allyl ether is disclosed comprising reacting (a) a phenolic compound with (b) an allyl acetate in the presence of (c) an allylation catalyst selected from a ruthenium or rare earth metal catalyst complex comprising at least one stable ligand containing a substituted aromatic-containing moiety, wherein the aromatic-containing ligand is cyclopentadienyl (Cp), pentamethylcyclopentadienyl (Cp*), indenyl (In), or 9-fluorenyl (F1), or a substituted olefinic-containing ligand, wherein the olefinic moiety is a cyclooctadienyl (COD) or butyldienyl moiety or substituted olefinic-containing ligands. A process for the preparation of an epoxy-containing compound is disclosed comprising epoxidizing the aryl allyl ether compound made according to this invention. |
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AbstractList | A process for preparing an aryl allyl ether is disclosed comprising reacting (a) a phenolic compound with (b) an allyl acetate in the presence of (c) an allylation catalyst selected from a ruthenium or rare earth metal catalyst complex comprising at least one stable ligand containing a substituted aromatic-containing moiety, wherein the aromatic-containing ligand is cyclopentadienyl (Cp), pentamethylcyclopentadienyl (Cp*), indenyl (In), or 9-fluorenyl (F1), or a substituted olefinic-containing ligand, wherein the olefinic moiety is a cyclooctadienyl (COD) or butyldienyl moiety or substituted olefinic-containing ligands. A process for the preparation of an epoxy-containing compound is disclosed comprising epoxidizing the aryl allyl ether compound made according to this invention. |
Author | LIAO, ZENG K BORIACK, CLINTON J |
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DocumentTitleAlternate | Procédé pour la préparation d'éthers d'arylallyle Verfahren zur Herstellung von Arylallylethern |
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Snippet | A process for preparing an aryl allyl ether is disclosed comprising reacting (a) a phenolic compound with (b) an allyl acetate in the presence of (c) an... |
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SubjectTerms | ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY HETEROCYCLIC COMPOUNDS METALLURGY ORGANIC CHEMISTRY |
Title | Process for preparing aryl allyl ethers |
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