Cracking catalyst, its preparation and use

New catalyst compositions of superior hydrothermal stability, which evidence increased gasoline plus distillate yields, improved coke selectivity and reduced C4- Gas yields, are based on framework dealuminated faujasitic zeolites having a framework silica to alumina molar ratio of from about 5 to l0...

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Bibliographic Details
Main Authors HERBST, JOSEPH ANTHONY, BUNDENS, ROBERT GLENN
Format Patent
LanguageEnglish
French
German
Published 24.02.1988
Subjects
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
CRACKING HYDROCARBON OILS
FUELS
LUBRICANTS
METALLURGY
MINERAL WAXES
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION
RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES
REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS
REFORMING OF NAPHTHA
TECHNICAL GASES CONTAINING CARBON MONOXIDE
THEIR RELEVANT APPARATUS
TRANSPORTING
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Summary:New catalyst compositions of superior hydrothermal stability, which evidence increased gasoline plus distillate yields, improved coke selectivity and reduced C4- Gas yields, are based on framework dealuminated faujasitic zeolites having a framework silica to alumina molar ratio of from about 5 to l00. In a preferred embodiment, an "ultrastable Y" composited with a matrix is subjected to a treatment with a source of aluminum and rare earth compounds followed by hydrothermal treatments to improve the hydrothermal stability and selectivity of the catalyst for catalytic cracking. This is evidenced by higher gasoline plus distillate yields and lower coke and gas production at lower catalyst usage per barrel of feed relative to commercial cracking catalysts currently being used.
Bibliography:Application Number: EP19870307244