Short residence time coal liquefaction process including catalytic hydrogenation
Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone (26, alone, or 26 together with 42), the hydrogen pressure in...
Saved in:
Main Authors | , |
---|---|
Format | Patent |
Language | English French German |
Published |
17.03.1982
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone (26, alone, or 26 together with 42), the hydrogen pressure in the preheating-reaction zone being at least 1500 psig (105 kg/cm2), reacting the slurry in the preheating-reaction zone (26, or 26 with 42) at a temperature in the range of between about 455° and about 500°C to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid (40, 68) to substantially immediately reduce the temperature of the reaction effluent to below 425°C to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C5 - 454°C is an amount at least equal to that obtainable by performing the process under the same conditions except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent (83) and recycled as process solvent (16). The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance. Normally solid deashed coal is produced which possesses a high benzene soluble content which is highly amenable to catalytic hydroconversion (90) to solvent boiling range liquid (98) which can be used to make up any recycle solvent deficiency (99) and to maintain the overall solvent balance of the process. Likewise, when the short residence time process provides sufficient recycle solvent, distillate liquid can be recovered as an upgraded liquid fuel product of the process. |
---|---|
AbstractList | Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle solvent oil and/or slurry together with hydrogen to a preheating-reaction zone (26, alone, or 26 together with 42), the hydrogen pressure in the preheating-reaction zone being at least 1500 psig (105 kg/cm2), reacting the slurry in the preheating-reaction zone (26, or 26 with 42) at a temperature in the range of between about 455° and about 500°C to dissolve the coal to form normally liquid coal and normally solid dissolved coal. A total slurry residence time is maintained in the reaction zone ranging from a finite value from about 0 to about 0.2 hour, and reaction effluent is continuously and directly contacted with a quenching fluid (40, 68) to substantially immediately reduce the temperature of the reaction effluent to below 425°C to substantially inhibit polymerization so that the yield of insoluble organic matter comprises less than 9 weight percent of said feed coal on a moisture-free basis. The reaction is performed under conditions of temperature, hydrogen pressure and residence time such that the quantity of distillate liquid boiling within the range C5 - 454°C is an amount at least equal to that obtainable by performing the process under the same conditions except for a longer total slurry residence time, e.g., 0.3 hour. Solvent boiling range liquid is separated from the reaction effluent (83) and recycled as process solvent (16). The amount of solvent boiling range liquid is sufficient to provide at least 80 weight percent of that required to maintain the process in overall solvent balance. Normally solid deashed coal is produced which possesses a high benzene soluble content which is highly amenable to catalytic hydroconversion (90) to solvent boiling range liquid (98) which can be used to make up any recycle solvent deficiency (99) and to maintain the overall solvent balance of the process. Likewise, when the short residence time process provides sufficient recycle solvent, distillate liquid can be recovered as an upgraded liquid fuel product of the process. |
Author | ANDERSON, RAYMOND PAUL WRIGHT, CHARLES HUBERT |
Author_xml | – fullname: WRIGHT, CHARLES HUBERT – fullname: ANDERSON, RAYMOND PAUL |
BookMark | eNqNyjsKwkAQANAttPB3h7mAED8htUjEMqB9GCaTZGCdWXc3RW4vggewes1bu4Wa8so1j9FihshJOlZiyPJiIEMPXt4T90hZTCFEI04JRMlPnegAhBn9nIVgnLtoAyt-59Yte_SJdz83Dm7183rfc7CWU0Bi5dzWTVGcq7I6XI6nP8oHv7o5mA |
ContentType | Patent |
DBID | EVB |
DatabaseName | esp@cenet |
DatabaseTitleList | |
Database_xml | – sequence: 1 dbid: EVB name: esp@cenet url: http://worldwide.espacenet.com/singleLineSearch?locale=en_EP sourceTypes: Open Access Repository |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Medicine Chemistry Sciences |
DocumentTitleAlternate | Procédé de liquéfaction de charbon à court temps de séjour utilisant une hydrogénation catalytique. Kohleverflüssigungsverfahren mit kurzer Verweilzeit, das eine katalytische Hydrierung einschliesst. |
ExternalDocumentID | EP0047571A2 |
GroupedDBID | EVB |
ID | FETCH-epo_espacenet_EP0047571A23 |
IEDL.DBID | EVB |
IngestDate | Fri Jul 19 13:59:47 EDT 2024 |
IsOpenAccess | true |
IsPeerReviewed | false |
IsScholarly | false |
Language | English French German |
LinkModel | DirectLink |
MergedId | FETCHMERGED-epo_espacenet_EP0047571A23 |
Notes | Application Number: EP19810301728 |
OpenAccessLink | https://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19820317&DB=EPODOC&CC=EP&NR=0047571A2 |
ParticipantIDs | epo_espacenet_EP0047571A2 |
PublicationCentury | 1900 |
PublicationDate | 19820317 |
PublicationDateYYYYMMDD | 1982-03-17 |
PublicationDate_xml | – month: 03 year: 1982 text: 19820317 day: 17 |
PublicationDecade | 1980 |
PublicationYear | 1982 |
RelatedCompanies | THE PITTSBURGH & MIDWAY COAL MINING COMPANY |
RelatedCompanies_xml | – name: THE PITTSBURGH & MIDWAY COAL MINING COMPANY |
Score | 2.3600042 |
Snippet | Normally solid dissolved coal product and a distillate liquid product are produced by continuously passing a feed slurry comprising raw feed coal and a recycle... |
SourceID | epo |
SourceType | Open Access Repository |
SubjectTerms | CHEMISTRY CRACKING HYDROCARBON OILS FUELS LUBRICANTS METALLURGY MINERAL WAXES PEAT PETROLEUM, GAS OR COKE INDUSTRIES PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE |
Title | Short residence time coal liquefaction process including catalytic hydrogenation |
URI | https://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=19820317&DB=EPODOC&locale=&CC=EP&NR=0047571A2 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV1LS8NAEB5KFfWmVbG-2IPkFmRjHvQQxOZBEdoGrdJb2d0kNBCS0KZI_72zm7R60duSwJIdZuab2cx8A_BgDdIE1cTQMVs2MEHhVOcp5zq1U1kuFscDJpuTxxN79GG-zq15B7JdL4ziCf1S5IhoUQLtvVb-uvq5xPJVbeX6kWf4qHwOZ66vxU27GMIZ4qHmD90gmvpTT_M8XGmTN1eyIloOfUFvfSCjaEmzH3wOZVNK9RtRwlM4jHCzoj6DTlL04NjbDV7rwdG4_d-Ny9b01ucQvS8xUiaYHTdjQImcCk9EyXKSSw7WtkOBVE3lP8kKkW8kMBF1Q7NFBSHLbbwqUWPUAS-AhMHMG-n4aYu9GBZBtD_E0yV0i7JIroCgl2CGYCZNhWNaTDA7VZTrLMZIjSe0D_0_t7n-590NnEh5ynIr6txCt15tkjvE35rfK8l9A0jmjHk |
link.rule.ids | 230,309,786,891,25594,76904 |
linkProvider | European Patent Office |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV3NS8MwFH-MKc6bTsX5mYP0ViRzbdmhiGs7pu6j6JTdRpK2rFDasnXI_ntf0m560VtoIDSP95GXvN_vAdwZ3ShENWnrmC23MUHhVOcR5zo1I1kuFgRdJsHJo7E5-Oi8zIxZDeItFkbxhH4pckS0KIH2Xih_nf9cYrmqtnJ1z2P8lD32p7arBSVcDMMZxkPN7dmeP3EnjuY4ONLGb7ZkRTQs-oTees_CjFDS7HufPQlKyX9HlP4R7Pu4WFocQy1Mm9Bwto3XmnAwqt67cViZ3uoE_PcFnpQJZsdlG1Aiu8ITkbGEJJKDtUIokLys_CdxKpK1DExE3dBsUEHIYhMsM9QYtcFTIH1v6gx0_LX5Tgxzz99t4uEM6mmWhudA0EuwtmAdGgmrYzDBzEhRrrMAT2o8pC1o_bnMxT9zt9AYTEfD-fB5_HoJh1K2svSKWldQL5br8BpjccFvlBS_AQBwj2Q |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Apatent&rft.title=Short+residence+time+coal+liquefaction+process+including+catalytic+hydrogenation&rft.inventor=WRIGHT%2C+CHARLES+HUBERT&rft.inventor=ANDERSON%2C+RAYMOND+PAUL&rft.date=1982-03-17&rft.externalDBID=A2&rft.externalDocID=EP0047571A2 |