Luminescent material and luminescent element comprising the same
A light emitting material comprising a conjugated polymer compound (A) containing an aromatic ring in the main chain and a compound (B) showing light emission from the triplet excited state, wherein an energy difference between the vacuum level and the lowest unoccupied orbital (LUMO) level in the g...
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Format | Patent |
Language | English |
Published |
18.10.2006
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Abstract | A light emitting material comprising a conjugated polymer compound (A) containing an aromatic ring in the main chain and a compound (B) showing light emission from the triplet excited state, wherein an energy difference between the vacuum level and the lowest unoccupied orbital (LUMO) level in the ground state, calculated by a computational chemical means, is 1.3 eV or more, or an energy difference between the vacuum level and the lowest unoccupied orbital (LUMO) level in the ground state, experimentally measured, is 2.2 eV or more, in the polymer compound (A), and either the following (Condition 1) or the following (Condition 2) or both of them are satisfied. (Condition 1): Energy (ESA0) in the ground state of the polymer compound (A), energy (ETA) in the lowest excited triplet state of the polymer compound (A), energy (ESB0) in the ground state of the compound (B) and energy (ETB) in the lowest excited triplet state of the compound (B) satisfy the relation (Eq 1 ): ETA-ESA0>ETB-ESB0 (Eq1) (Condition 2): The ratio PLA/PLB of photoluminescence intensity (PLA) of the polymer compound (A) to photoluminescence intensity (PLB) of the compound (B) showing light emission from the triplet excited state is 0.8 or less. |
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AbstractList | A light emitting material comprising a conjugated polymer compound (A) containing an aromatic ring in the main chain and a compound (B) showing light emission from the triplet excited state, wherein an energy difference between the vacuum level and the lowest unoccupied orbital (LUMO) level in the ground state, calculated by a computational chemical means, is 1.3 eV or more, or an energy difference between the vacuum level and the lowest unoccupied orbital (LUMO) level in the ground state, experimentally measured, is 2.2 eV or more, in the polymer compound (A), and either the following (Condition 1) or the following (Condition 2) or both of them are satisfied. (Condition 1): Energy (ESA0) in the ground state of the polymer compound (A), energy (ETA) in the lowest excited triplet state of the polymer compound (A), energy (ESB0) in the ground state of the compound (B) and energy (ETB) in the lowest excited triplet state of the compound (B) satisfy the relation (Eq 1 ): ETA-ESA0>ETB-ESB0 (Eq1) (Condition 2): The ratio PLA/PLB of photoluminescence intensity (PLA) of the polymer compound (A) to photoluminescence intensity (PLB) of the compound (B) showing light emission from the triplet excited state is 0.8 or less. |
Author | SEKINE CHIZU,AKINO NABUHIKO,MIKAMI SATOSHI |
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Snippet | A light emitting material comprising a conjugated polymer compound (A) containing an aromatic ring in the main chain and a compound (B) showing light emission... |
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SubjectTerms | ADHESIVES CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON CORRECTING FLUIDS DYES ELECTRIC HEATING ELECTRIC LIGHTING NOT OTHERWISE PROVIDED FOR ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR ELECTRICITY FILLING PASTES INKS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING POLISHES THEIR PREPARATION OR CHEMICAL WORKING-UP USE OF MATERIALS THEREFOR WOODSTAINS |
Title | Luminescent material and luminescent element comprising the same |
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