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Abstract A light emitting material comprising a conjugated polymer compound (A) containing an aromatic ring in the main chain and a compound (B) showing light emission from the triplet excited state, wherein an energy difference between the vacuum level and the lowest unoccupied orbital (LUMO) level in the ground state, calculated by a computational chemical means, is 1.3 eV or more, or an energy difference between the vacuum level and the lowest unoccupied orbital (LUMO) level in the ground state, experimentally measured, is 2.2 eV or more, in the polymer compound (A), and either the following (Condition 1) or the following (Condition 2) or both of them are satisfied. (Condition 1): Energy (ESA0) in the ground state of the polymer compound (A), energy (ETA) in the lowest excited triplet state of the polymer compound (A), energy (ESB0) in the ground state of the compound (B) and energy (ETB) in the lowest excited triplet state of the compound (B) satisfy the relation (Eq 1 ): ETA-ESA0>ETB-ESB0 (Eq1) (Condition 2): The ratio PLA/PLB of photoluminescence intensity (PLA) of the polymer compound (A) to photoluminescence intensity (PLB) of the compound (B) showing light emission from the triplet excited state is 0.8 or less.
AbstractList A light emitting material comprising a conjugated polymer compound (A) containing an aromatic ring in the main chain and a compound (B) showing light emission from the triplet excited state, wherein an energy difference between the vacuum level and the lowest unoccupied orbital (LUMO) level in the ground state, calculated by a computational chemical means, is 1.3 eV or more, or an energy difference between the vacuum level and the lowest unoccupied orbital (LUMO) level in the ground state, experimentally measured, is 2.2 eV or more, in the polymer compound (A), and either the following (Condition 1) or the following (Condition 2) or both of them are satisfied. (Condition 1): Energy (ESA0) in the ground state of the polymer compound (A), energy (ETA) in the lowest excited triplet state of the polymer compound (A), energy (ESB0) in the ground state of the compound (B) and energy (ETB) in the lowest excited triplet state of the compound (B) satisfy the relation (Eq 1 ): ETA-ESA0>ETB-ESB0 (Eq1) (Condition 2): The ratio PLA/PLB of photoluminescence intensity (PLA) of the polymer compound (A) to photoluminescence intensity (PLB) of the compound (B) showing light emission from the triplet excited state is 0.8 or less.
Author SEKINE CHIZU,AKINO NABUHIKO,MIKAMI SATOSHI
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Snippet A light emitting material comprising a conjugated polymer compound (A) containing an aromatic ring in the main chain and a compound (B) showing light emission...
SourceID epo
SourceType Open Access Repository
SubjectTerms ADHESIVES
CHEMICAL PAINT OR INK REMOVERS
CHEMISTRY
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS
COMPOSITIONS BASED THEREON
CORRECTING FLUIDS
DYES
ELECTRIC HEATING
ELECTRIC LIGHTING NOT OTHERWISE PROVIDED FOR
ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
ELECTRICITY
FILLING PASTES
INKS
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
ORGANIC MACROMOLECULAR COMPOUNDS
PAINTS
PASTES OR SOLIDS FOR COLOURING OR PRINTING
POLISHES
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF MATERIALS THEREFOR
WOODSTAINS
Title Luminescent material and luminescent element comprising the same
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