Preparation method of catalyst for preparing methyl glycolate through selective hydrogenation of dimethyl oxalate
The invention discloses a preparation method of a catalyst for preparing methyl glycolate through selective hydrogenation of dimethyl oxalate, and relates to a preparation method of a catalyst. The preparation method of the catalyst comprises the following steps: firstly, preparing the main active c...
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Format | Patent |
Language | Chinese English |
Published |
05.08.2022
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Abstract | The invention discloses a preparation method of a catalyst for preparing methyl glycolate through selective hydrogenation of dimethyl oxalate, and relates to a preparation method of a catalyst. The preparation method of the catalyst comprises the following steps: firstly, preparing the main active component and the auxiliary active component into a salt-ammonia complex by adopting a precipitant, wherein the precipitant is ammonia water, urea and ammonium bicarbonate; alkoxy silane, high-purity fumed silica and high-purity silicon powder are used as silicon sources to be added into the complexing solution; the catalyst is prepared by the following steps: heating to remove ammonia, drying at 120 DEG C for 12 hours, and roasting at 450-750 DEG C for 4 hours, and the loading capacity of the active component is 0-25% (weight). When the catalyst is used, under the reaction conditions that the temperature is 200 DEG C, the pressure is 3 MPa and the liquid hourly space velocity is 2.1 gDMO/(gcata.h), the conversion r |
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AbstractList | The invention discloses a preparation method of a catalyst for preparing methyl glycolate through selective hydrogenation of dimethyl oxalate, and relates to a preparation method of a catalyst. The preparation method of the catalyst comprises the following steps: firstly, preparing the main active component and the auxiliary active component into a salt-ammonia complex by adopting a precipitant, wherein the precipitant is ammonia water, urea and ammonium bicarbonate; alkoxy silane, high-purity fumed silica and high-purity silicon powder are used as silicon sources to be added into the complexing solution; the catalyst is prepared by the following steps: heating to remove ammonia, drying at 120 DEG C for 12 hours, and roasting at 450-750 DEG C for 4 hours, and the loading capacity of the active component is 0-25% (weight). When the catalyst is used, under the reaction conditions that the temperature is 200 DEG C, the pressure is 3 MPa and the liquid hourly space velocity is 2.1 gDMO/(gcata.h), the conversion r |
Author | ZHANG HONGJIE MENG DAN WANG YUNKAI CHEN SHULE ZHANG MEILING XU WENJIAN SAN AKIHIRO |
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DocumentTitleAlternate | 一种草酸二甲酯选择性加氢制乙醇酸甲酯催化剂制备方法 |
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Snippet | The invention discloses a preparation method of a catalyst for preparing methyl glycolate through selective hydrogenation of dimethyl oxalate, and relates to a... |
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Title | Preparation method of catalyst for preparing methyl glycolate through selective hydrogenation of dimethyl oxalate |
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