3-(carboxylmethoxyl)-2-naphthoic acid copper complex and preparation method thereof

• Main Authors: Wang Jinhua, Zhang Zhenhao, Wan Wenzhu, Wang Yongtao, Tang Guimei
• Format: Patent
• Language: Chinese; English
• Published: 03.08.2016
• Subjects: ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM; CHEMISTRY; METALLURGY; ORGANIC CHEMISTRY

The invention discloses a naphthalic acid copper complex and a preparation method thereof. The chemical formula of the complex is [Cu(32AA)(H2O)]; wherein 32AA represents 3-(carboxylmethoxyl)-2-naphthoic acid. The provided copper complex is prepared from divalent copper and 3-(carboxylmethoxyl)-2-naphthoic acid through a solvothermal method. The complex is a monocrystalline complex obtained through molecule self assembly. The preparation method has the advantages of easily available synthesis raw materials, low cost, and high purity, moreover, the complex is easy to prepare, and the yield, stability, and crystallization degree are high. Furthermore, the complex has a good potential application value in the magnetic field. 本发明公开了种萘二酸铜配合物及其制备方法。其化学式为[Cu(32AA)(HO)]，其中32AA为3?(羧甲氧基)?2萘甲酸。本发明提供的铜配合物为二价铜与3?(羧甲氧基)?2萘甲酸通过溶剂热法得到。本发明的配合物是经过分子自组装而成的单晶配合物。所述配合物合成原料易得，成本低，纯度大，且该配合物易制备，高产率，高稳定性及高结晶度。另外，该配合物在磁学领域具有非常好的潜在应用价值。