Synthetic method of benzoate compound

The invention provides a synthetic method of a benzoate compound. The benzoate compound is synthesized in high yield and in high conversion rate at a mild condition by taking a benzonitrile compound and an alcohol or phenolic compound as raw materials, by taking cheap and easily available copper as...

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Main Authors HAN LIBIAO, ZHOU YONGBO, DONG JIANYU, LI ZHONGWEN, JI FANGYAN, CHEN XIULING, YIN SHUANGFENG
Format Patent
LanguageEnglish
Published 09.09.2015
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
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Abstract The invention provides a synthetic method of a benzoate compound. The benzoate compound is synthesized in high yield and in high conversion rate at a mild condition by taking a benzonitrile compound and an alcohol or phenolic compound as raw materials, by taking cheap and easily available copper as a catalyst, and by taking green and environment-friendly oxygen as an oxidizing agent. One of the raw materials in the method can not only result from the alcohol compound, but also from the phenolic compound, so that the range of substrates is greatly widened. The problems that most methods are not wildly suitable for functional groups and that specific reaction conditions, such as taking an expensive transition metal as the catalyst, and using a toxic reagent, are needed are overcome. The synthetic method has a certain industrial application value.
AbstractList The invention provides a synthetic method of a benzoate compound. The benzoate compound is synthesized in high yield and in high conversion rate at a mild condition by taking a benzonitrile compound and an alcohol or phenolic compound as raw materials, by taking cheap and easily available copper as a catalyst, and by taking green and environment-friendly oxygen as an oxidizing agent. One of the raw materials in the method can not only result from the alcohol compound, but also from the phenolic compound, so that the range of substrates is greatly widened. The problems that most methods are not wildly suitable for functional groups and that specific reaction conditions, such as taking an expensive transition metal as the catalyst, and using a toxic reagent, are needed are overcome. The synthetic method has a certain industrial application value.
Author HAN LIBIAO
LI ZHONGWEN
CHEN XIULING
DONG JIANYU
ZHOU YONGBO
YIN SHUANGFENG
JI FANGYAN
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– fullname: CHEN XIULING
– fullname: YIN SHUANGFENG
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Snippet The invention provides a synthetic method of a benzoate compound. The benzoate compound is synthesized in high yield and in high conversion rate at a mild...
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SubjectTerms ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
Title Synthetic method of benzoate compound
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