Prometryn molecular imprinting solid phase extraction column and application method thereof

• Main Authors: YI LINGXIAO, SHAO YUXIU, CHEN GUANHUA, FANG ROU, ZHANG LI
• Format: Patent
• Language: Chinese; English
• Published: 11.12.2013
• Subjects: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY; INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIRCHEMICAL OR PHYSICAL PROPERTIES; MEASURING; PERFORMING OPERATIONS; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; PHYSICS; TESTING; THEIR RELEVANT APPARATUS; TRANSPORTING

The invention relates to the technical field of solid phase extraction, and particularly discloses a prometryn molecular imprinting solid phase extraction column and an application method thereof. With prometryn as a template, methacrylic acid as a functional monomer, glycol dimethyl methacrylate as a cross-linking agent, azodiisobutyronitrile as an initiating agent, dichloromethane as a solvent, a precipitation polymerization method is adopted to prepare prometryn molecular imprintingpolymeric microsphere; microballoons are uniformly filled in the solid phase extraction column, thus obtaining the prometryn molecular imprinting solid phase extraction column; dichloromethane is utilized as, residuals of simazine, atrazine, szimetrin, propazine, ametryn, terbuthylazine, prometryn and terbutryn in a grain sample are simultaneously enriched and purified by taking a sample solvent and dichloromethane-acetonitrile as a leaching solvent and taking methyl alcohol-water as an eluting solvent, when used together with a