Associative thickening agent made of acid monomers, associative monomers, and non-ionic monomers

• Main Authors: GUBAYDULLIN ILSHAT, BOTHE MARC, HANCIOGULLARI HARUTYUN, SEYFFER HERMANN, ZACHARIAS PHILIPP
• Format: Patent
• Language: English
• Published: 25.02.2015
• Subjects: CHEMISTRY; COMPOSITIONS BASED THEREON; IMPREGNATING OR COATING OF PAPER; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; PAPER NOT OTHERWISE PROVIDED FOR; PAPER-MAKING; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; PRODUCTION OF CELLULOSE; PULP COMPOSITIONS; TEXTILES; THEIR PREPARATION OR CHEMICAL WORKING-UP; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G

As associative thickener obtainable by free radical polymerization, the preparation thereof and the use thereof in paper coating slips are described. The associative thickener is formed from (a) acid monomers selected from ethylenically unsaturated C3- to C8-carboxylic acids, (b) associative monomers of the general formula H2C CR1-COO-(EO)n-(PO)m-R2, in which R1 is hydrogen or methyl, n is a number of at least two, m is a number from zero to 50, EO is an ethylene oxide group, PO is a propylene oxide group and R2 is a C8-C30-alkyl group or a C8-C30-alkaryl group, and (c) nonionic, copolymerizable monomers differing from a) and b), the reaction product having been reacted, after the polymerization, with initiators forming nonionic radicals.