processo para melhorar o desempenho de barreira de um objeto revestido por plasma compreendendo uma poliolefina, artigo de manufatura e método para melhorar a resistência a manchas de um objeto comprendendo uma resina poliolefínica

• Main Author: Angela N. Taha
• Format: Patent
• Language: Portuguese
• Published: 24.09.2019
• Subjects: AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL; CHEMISTRY; COMPOSITIONS BASED THEREON; GENERAL PROCESSES OF COMPOUNDING; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; PERFORMING OPERATIONS; PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR; SHAPING OR JOINING OF PLASTICS; SPRAYING OR ATOMISING IN GENERAL; THEIR PREPARATION OR CHEMICAL WORKING-UP; TRANSPORTING; WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL; WORKING-UP

A process for improving the barrier performance of a plasma coated object comprising a polyolefin is disclosed. The process involves ensuring that the surface of the object to be coated is smooth as characterized by having a root-mean-square surface roughness that varies by less than the thickness of the coating to be applied, typically less than 100 nm. The invention also relates to a process for improving the stain resistance of polyolefin based articles comprising plasma polymerizing an organosilicon compound under conditions to deposit a polyorganosiloxane layer onto the article and/or (b) plasma polymerizing a organosilicon compound under conditions to deposit a silicon oxide layer directly on the article or onto a polyorganosiloxane layer prepared according to step (a).