VANADIUM/ALUMINIUM COMPLEX BASED CATALYST FOR ETHYLENE COPOLYMERIZATION
A catalyst composition comprising: (i) a complex comprised of V2X3(ED)m and AlCl2R2 wherein X = Cl, Br, or I, or mixtures thereof ED = an electron donor, which is an ether, a phosphine, a ketone, an isocyanide, or an ester, said electron donor having 2 to 20 carbon atoms R = an alkyl having up to 14...
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Main Author | |
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Format | Patent |
Language | English |
Published |
14.06.1990
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Edition | 5 |
Subjects | |
Online Access | Get full text |
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Abstract | A catalyst composition comprising: (i) a complex comprised of V2X3(ED)m and AlCl2R2 wherein X = Cl, Br, or I, or mixtures thereof ED = an electron donor, which is an ether, a phosphine, a ketone, an isocyanide, or an ester, said electron donor having 2 to 20 carbon atoms R = an alkyl having up to 14 carbon atoms m = an integer from 3 to 6, said complex impregnated into an inorganic oxide support; (ii) sufficient trialkylaluminum compound adsorbed on the inorganic oxide support to provide a molar ratio of adsorbed trialkylaluminum compound to vanadium of about 2.5:1 to about 10:1; (iii) a halocarbon promoter; and (iv) a hydrocarbyl aluminum cocatalyst. ( |
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AbstractList | A catalyst composition comprising: (i) a complex comprised of V2X3(ED)m and AlCl2R2 wherein X = Cl, Br, or I, or mixtures thereof ED = an electron donor, which is an ether, a phosphine, a ketone, an isocyanide, or an ester, said electron donor having 2 to 20 carbon atoms R = an alkyl having up to 14 carbon atoms m = an integer from 3 to 6, said complex impregnated into an inorganic oxide support; (ii) sufficient trialkylaluminum compound adsorbed on the inorganic oxide support to provide a molar ratio of adsorbed trialkylaluminum compound to vanadium of about 2.5:1 to about 10:1; (iii) a halocarbon promoter; and (iv) a hydrocarbyl aluminum cocatalyst. ( |
Author | FRANCIS GREGORY STAKEM |
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RelatedCompanies | UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC |
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Snippet | A catalyst composition comprising: (i) a complex comprised of V2X3(ED)m and AlCl2R2 wherein X = Cl, Br, or I, or mixtures thereof ED = an electron donor, which... |
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SubjectTerms | CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP |
Title | VANADIUM/ALUMINIUM COMPLEX BASED CATALYST FOR ETHYLENE COPOLYMERIZATION |
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