KATALYSATORSYSTEM ZUR AEOROBEN OXIDATION VON PRIMÄREN UND SEKUNDÄREN ALKOHOLEN

• Main Authors: JACKSON, HANDLEY, TANIELYAN, SETRAK, FURLONG, KENNETH, AUGUSTINE, ROBERT, PRAKASH, INDRA
• Format: Patent
• Language: German
• Published: 15.09.2010
• Subjects: ACYCLIC OR CARBOCYCLIC COMPOUNDS; CHEMISTRY; METALLURGY; ORGANIC CHEMISTRY

The present invention relates to a process of oxidation of alcohols selectively to aldehydes or ketones with molecular oxygen using a TEMPO based catalyst, Fe-bipyridyl or Fe-phenantroline co-catalyst and N-bromosuccinimide promoter in acetic acid solvent. The oxidation takes places at high rates an...