Synergistic catalytic elimination of NOx and VOCs: State of the art and open challenges

Nitrogen oxide (NOx) and volatile organic compounds (VOCs) pose a severe threat to human health and eco-environment. Synergistic catalytic degradation has sparked significant interest in multipollutant control, especially for industries with limited space for technological upgrades to satisfy more s...

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Published inSurfaces and interfaces Vol. 51
Main Authors Chu, Peiqi, Zhang, Long, Wang, Zhiwei, Wei, Lu, Liu, Yuxi, Dai, Hongxing, Duan, Erhong, Deng, Jiguang
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.08.2024
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Abstract Nitrogen oxide (NOx) and volatile organic compounds (VOCs) pose a severe threat to human health and eco-environment. Synergistic catalytic degradation has sparked significant interest in multipollutant control, especially for industries with limited space for technological upgrades to satisfy more stringent emission regulations. However, it is still in the early stages of development and faces many issues and challenges, such as highly efficient catalyst design, uncertain reaction mechanism for multipollutant removal, impact of other components in complex flue gas on the synergistic catalytic degradation, and environmental risk assessment of synergistic catalytic degradation in terms of byproduct. This review summarizes the advantage and disadvantage of common reported catalysts for synergistic catalytic degradation, discusses the factors affecting the performance and the optimization technique from the standpoint of acidity and redox characteristics, refines the synergistic catalytic degradation mechanism and deactivation process due to the presence of toxic component, and highlights the category and formation mechanism of the potential byproduct during the synergistic catalytic degradation. It will provide a reference for ongoing in-depth research and real-world industrial application in the area of synergistic catalytic degradation of NOx and VOCs. [Display omitted]
AbstractList Nitrogen oxide (NOx) and volatile organic compounds (VOCs) pose a severe threat to human health and eco-environment. Synergistic catalytic degradation has sparked significant interest in multipollutant control, especially for industries with limited space for technological upgrades to satisfy more stringent emission regulations. However, it is still in the early stages of development and faces many issues and challenges, such as highly efficient catalyst design, uncertain reaction mechanism for multipollutant removal, impact of other components in complex flue gas on the synergistic catalytic degradation, and environmental risk assessment of synergistic catalytic degradation in terms of byproduct. This review summarizes the advantage and disadvantage of common reported catalysts for synergistic catalytic degradation, discusses the factors affecting the performance and the optimization technique from the standpoint of acidity and redox characteristics, refines the synergistic catalytic degradation mechanism and deactivation process due to the presence of toxic component, and highlights the category and formation mechanism of the potential byproduct during the synergistic catalytic degradation. It will provide a reference for ongoing in-depth research and real-world industrial application in the area of synergistic catalytic degradation of NOx and VOCs. [Display omitted]
ArticleNumber 104718
Author Dai, Hongxing
Deng, Jiguang
Zhang, Long
Chu, Peiqi
Wei, Lu
Duan, Erhong
Liu, Yuxi
Wang, Zhiwei
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  organization: Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Beijing on Regional Air Pollution Control, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Department of Chemical Engineering, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
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  givenname: Zhiwei
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  givenname: Lu
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  organization: Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Beijing on Regional Air Pollution Control, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Department of Chemical Engineering, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
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  givenname: Yuxi
  surname: Liu
  fullname: Liu, Yuxi
  organization: Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Beijing on Regional Air Pollution Control, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Department of Chemical Engineering, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
– sequence: 6
  givenname: Hongxing
  surname: Dai
  fullname: Dai, Hongxing
  organization: Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Beijing on Regional Air Pollution Control, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Department of Chemical Engineering, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
– sequence: 7
  givenname: Erhong
  surname: Duan
  fullname: Duan, Erhong
  email: duan_eh@163.com
  organization: School of Environmental Science and Engineering, Hebei University of Science and Technology, 26th Yuxiang Street, Shijiazhuang, Hebei 050018, China
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  givenname: Jiguang
  orcidid: 0000-0001-7768-3688
  surname: Deng
  fullname: Deng, Jiguang
  email: jgdeng@bjut.edu.cn
  organization: Beijing Key Laboratory for Green Catalysis and Separation, Key Laboratory of Beijing on Regional Air Pollution Control, Key Laboratory of Advanced Functional Materials, Education Ministry of China, Department of Chemical Engineering, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
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Keywords VOCs
Catalysts
reaction mechanism
NOx
Synergistic catalytic degradation
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Snippet Nitrogen oxide (NOx) and volatile organic compounds (VOCs) pose a severe threat to human health and eco-environment. Synergistic catalytic degradation has...
SourceID elsevier
SourceType Publisher
SubjectTerms Catalysts
NOx
reaction mechanism
Synergistic catalytic degradation
VOCs
Title Synergistic catalytic elimination of NOx and VOCs: State of the art and open challenges
URI https://dx.doi.org/10.1016/j.surfin.2024.104718
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