Polymerization of sterically hindered a-olefins with single-site group 4 metal catalyst precursors

• Published in: Polyolefins journal Vol. 4; no. 1; pp. 123 - 136
• Main Authors: Gabriel Theurkauff, Katty Den Dauw, Olivier Miserque, Aurélien Vantomme, Jean-Michel Brusson, Jean-François Carpentier, Evgeny Kirillov
• Format: Journal Article
• Language: English
• Published: Iran Polymer and Petrochemical Institute 01.01.2016
• Subjects: 3-methylbut-1-ene; catalysis; NMR analysis; polymerization; vinylcyclohexane

A variety of group 4 metal catalytic systems (C2-symmetric {EBTHI}-, {SBI}-type zirconocene complexes (C2-1–4); C1-symmetric (C1-5–8) and Cs-symmetric (Cs-9) {Cp/Flu}-type zirconocene complexes; Cp*2ZrCl2 (Cp* 2-10)), half-metallocene complexes (CpTiCl3, HM-11), constrained-geometry (CGC-12) titaniu...