Impact of sintering time on structure and electrical properties of Pb-free BNT-BKT-SZ ceramics

The work focuses on preparing and characterising BNT-based ceramics via a solidstate method. To investigate the phase, microstructure, and physical and electrical properties of BNT-based ceramics.Lead-free piezoelectric bismuth sodium titanate – bismuth potassium titanate – stronsium zirconate (BNT-...

Full description

Saved in:
Bibliographic Details
Published inArchives of materials science and engineering Vol. 125; no. 2
Main Authors Manotham, S., Butnoi, P., Khieokae, M., Paengchit, P., Prajansri, P.
Format Journal Article
LanguageEnglish
Published 01.03.2024
Online AccessGet full text

Cover

Abstract The work focuses on preparing and characterising BNT-based ceramics via a solidstate method. To investigate the phase, microstructure, and physical and electrical properties of BNT-based ceramics.Lead-free piezoelectric bismuth sodium titanate – bismuth potassium titanate – stronsium zirconate (BNT-BKT-SZ) ceramics were fabricated by the solid-state reaction method. The effect of sintering temperature with soaking times of 2, 4, and 6 h at 1150C on structural, microstructure, density, porosity, and electrical properties was examined. The phase formation of the ceramics was examined using X-ray diffraction (XRD). Scanning electron microscopy (SEM) (JEOL JSM5910LV) was employed to investigate ceramic microstructure. The bulk density and mechanical properties of the sample were measured using Archimedes’ method, respectively. The electrical properties of ceramics, such as dielectrics, ferroelectrics, and piezoelectrics, were investigated.XRD showed all samples had a single perovskite structure and no secondary phase. All sintered samples at different temperatures have a coexisting phase boundary between the rhombohedral phase and the tetragonal phase. The sintered ceramic at 1150C with a soaking time of 4 h shows a maximum density of 5.89 g/cm3. In addition, the temperature at which the sintering process is carried out substantially impacts the electrical characteristics. Dielectric and electric field-induced strain (Smax) properties that sintered at 1150C with a soaking time of 4 h exhibited the highest values of 4.489 and 0.39% (d33* of 650 pm/V), respectively.The impact of the coercive field on the electrical breakdown characteristics of ceramics should be investigated further in the course of research that has to be carried out.The characterisation confirmed the effects of sintering temperature on the physical, phase, microstructure, and electrical properties of BNT-based ceramics.Such research demonstrates a suitable sintering temperature for producing BNT-BKT-SZ. The mechanical and electrical properties of a material are dependent on its sintering parameters. The ceramic system is suitable for piezoelectric and/or energy storage applications.
AbstractList The work focuses on preparing and characterising BNT-based ceramics via a solidstate method. To investigate the phase, microstructure, and physical and electrical properties of BNT-based ceramics.Lead-free piezoelectric bismuth sodium titanate – bismuth potassium titanate – stronsium zirconate (BNT-BKT-SZ) ceramics were fabricated by the solid-state reaction method. The effect of sintering temperature with soaking times of 2, 4, and 6 h at 1150C on structural, microstructure, density, porosity, and electrical properties was examined. The phase formation of the ceramics was examined using X-ray diffraction (XRD). Scanning electron microscopy (SEM) (JEOL JSM5910LV) was employed to investigate ceramic microstructure. The bulk density and mechanical properties of the sample were measured using Archimedes’ method, respectively. The electrical properties of ceramics, such as dielectrics, ferroelectrics, and piezoelectrics, were investigated.XRD showed all samples had a single perovskite structure and no secondary phase. All sintered samples at different temperatures have a coexisting phase boundary between the rhombohedral phase and the tetragonal phase. The sintered ceramic at 1150C with a soaking time of 4 h shows a maximum density of 5.89 g/cm3. In addition, the temperature at which the sintering process is carried out substantially impacts the electrical characteristics. Dielectric and electric field-induced strain (Smax) properties that sintered at 1150C with a soaking time of 4 h exhibited the highest values of 4.489 and 0.39% (d33* of 650 pm/V), respectively.The impact of the coercive field on the electrical breakdown characteristics of ceramics should be investigated further in the course of research that has to be carried out.The characterisation confirmed the effects of sintering temperature on the physical, phase, microstructure, and electrical properties of BNT-based ceramics.Such research demonstrates a suitable sintering temperature for producing BNT-BKT-SZ. The mechanical and electrical properties of a material are dependent on its sintering parameters. The ceramic system is suitable for piezoelectric and/or energy storage applications.
Author Khieokae, M.
Manotham, S.
Butnoi, P.
Prajansri, P.
Paengchit, P.
Author_xml – sequence: 1
  givenname: S.
  surname: Manotham
  fullname: Manotham, S.
– sequence: 2
  givenname: P.
  orcidid: 0000-0003-4353-7652
  surname: Butnoi
  fullname: Butnoi, P.
– sequence: 3
  givenname: M.
  surname: Khieokae
  fullname: Khieokae, M.
– sequence: 4
  givenname: P.
  surname: Paengchit
  fullname: Paengchit, P.
– sequence: 5
  givenname: P.
  surname: Prajansri
  fullname: Prajansri, P.
BookMark eNqdzk1KBDEQhuEsRnBGPYC7ukDaykz_2NsRRRFEsFezmBBjtUS6k6Yqs_D2GvAEbr5v9cKzUauYIil1bbBqWqxv0FQ7_B3Epq7arjErtTa3fae3XVufq43IF2Lbm22_VseneXE-QxpBQszEIX5CDjNBiiCZTz6fmMDFD6CJfObg3QQLp4U4B5ISvr7rkYlg_zLo_fOg3w7gid0cvFyqs9FNQld_f6HMw_1w96g9JxGm0S4cZsff1qAteIvGFrwteFvwu_80P-DyT_0
Cites_doi 10.1016/j.jallcom.2023.170913
10.5604/01.3001.0016.0027
10.1016/j.materresbull.2017.09.032
10.1007/s10854-021-06215-8
10.5604/01.3001.0015.4314
10.1016/j.jscs.2023.101617
10.5604/01.3001.0054.3211
10.1007/s11664-016-4811-z
10.1016/j.ceramint.2023.01.169
10.1016/j.matchemphys.2020.122966
10.1007/s11664-020-08174-y
10.1007/s40145-020-0430-5
10.4028/www.scientific.net/KEM.777.60
10.1016/j.materresbull.2023.112307
10.1016/j.ceramint.2020.06.187
10.2118/178296-MS
10.1016/j.heliyon.2023.e14761
10.1016/j.ceramint.2018.11.100
10.1016/j.jallcom.2015.06.151
10.1016/j.matlet.2020.127776
10.1063/1.4901549
10.5604/01.3001.0015.3583
10.1016/j.nanoen.2022.107580
10.1016/j.jmat.2021.08.002
10.1016/S1003-6326(14)63302-1
10.1016/j.jallcom.2016.06.290
10.1016/j.mtcomm.2023.106086
10.1111/j.1551-2916.2008.02469.x
10.1007/s10854-022-08541-x
10.1063/1.4790290
10.1016/j.ceramint.2020.07.099
10.1016/j.hydromet.2018.06.014
10.1016/j.matlet.2022.131950
10.1016/j.jallcom.2018.05.138
10.1016/j.ceramint.2015.10.055
10.4028/www.scientific.net/KEM.798.212
10.5604/01.3001.0053.9754
10.1016/j.jallcom.2017.12.175
10.1016/j.physb.2009.09.075
10.1016/j.matchemphys.2013.11.035
10.1016/j.matchemphys.2022.126326
ContentType Journal Article
DBID AAYXX
CITATION
DOI 10.5604/01.3001.0054.6751
DatabaseName CrossRef
DatabaseTitle CrossRef
DatabaseTitleList CrossRef
DeliveryMethod fulltext_linktorsrc
Discipline Engineering
ExternalDocumentID 10_5604_01_3001_0054_6751
GroupedDBID 23N
AAKDD
AAYXX
ACGFO
ADDVE
ALMA_UNASSIGNED_HOLDINGS
ARCSS
CITATION
E3Z
KQ8
OK1
RNS
TR2
Y2W
ID FETCH-crossref_primary_10_5604_01_3001_0054_67513
ISSN 1897-2764
IngestDate Wed Jul 17 13:02:22 EDT 2024
IsPeerReviewed true
IsScholarly true
Issue 2
Language English
LinkModel OpenURL
MergedId FETCHMERGED-crossref_primary_10_5604_01_3001_0054_67513
ORCID 0000-0003-4353-7652
ParticipantIDs crossref_primary_10_5604_01_3001_0054_6751
PublicationCentury 2000
PublicationDate 2024-3-1
PublicationDateYYYYMMDD 2024-03-01
PublicationDate_xml – month: 03
  year: 2024
  text: 2024-3-1
  day: 01
PublicationDecade 2020
PublicationTitle Archives of materials science and engineering
PublicationYear 2024
References 623090r19
623090r18
623090r17
623090r39
623090r7
623090r12
623090r34
623090r6
623090r11
623090r33
623090r9
623090r10
623090r32
623090r8
623090r31
623090r3
623090r16
623090r38
623090r2
623090r15
623090r37
623090r5
623090r14
623090r36
623090r4
623090r13
623090r35
623090r1
623090r41
623090r40
623090r29
623090r28
623090r23
623090r22
623090r21
623090r20
623090r42
623090r27
623090r26
623090r25
623090r24
623090r30
References_xml – ident: 623090r6
  doi: 10.1016/j.jallcom.2023.170913
– ident: 623090r4
  doi: 10.5604/01.3001.0016.0027
– ident: 623090r2
  doi: 10.1016/j.materresbull.2017.09.032
– ident: 623090r41
  doi: 10.1007/s10854-021-06215-8
– ident: 623090r3
  doi: 10.5604/01.3001.0015.4314
– ident: 623090r18
  doi: 10.1016/j.jscs.2023.101617
– ident: 623090r10
  doi: 10.5604/01.3001.0054.3211
– ident: 623090r42
  doi: 10.1007/s11664-016-4811-z
– ident: 623090r5
  doi: 10.1016/j.ceramint.2023.01.169
– ident: 623090r20
  doi: 10.1016/j.matchemphys.2020.122966
– ident: 623090r40
  doi: 10.1007/s11664-020-08174-y
– ident: 623090r39
  doi: 10.1007/s40145-020-0430-5
– ident: 623090r32
  doi: 10.4028/www.scientific.net/KEM.777.60
– ident: 623090r7
  doi: 10.1016/j.materresbull.2023.112307
– ident: 623090r19
  doi: 10.1016/j.ceramint.2020.06.187
– ident: 623090r29
  doi: 10.2118/178296-MS
– ident: 623090r13
  doi: 10.1016/j.heliyon.2023.e14761
– ident: 623090r21
  doi: 10.1016/j.ceramint.2018.11.100
– ident: 623090r26
  doi: 10.1016/j.jallcom.2015.06.151
– ident: 623090r16
  doi: 10.1016/j.matlet.2020.127776
– ident: 623090r38
  doi: 10.1063/1.4901549
– ident: 623090r11
  doi: 10.5604/01.3001.0015.3583
– ident: 623090r14
  doi: 10.1016/j.nanoen.2022.107580
– ident: 623090r17
  doi: 10.1016/j.jmat.2021.08.002
– ident: 623090r25
  doi: 10.1016/S1003-6326(14)63302-1
– ident: 623090r22
  doi: 10.1016/j.jallcom.2016.06.290
– ident: 623090r1
  doi: 10.1016/j.mtcomm.2023.106086
– ident: 623090r27
  doi: 10.1111/j.1551-2916.2008.02469.x
– ident: 623090r36
  doi: 10.1007/s10854-022-08541-x
– ident: 623090r37
  doi: 10.1063/1.4790290
– ident: 623090r24
  doi: 10.1016/j.ceramint.2020.07.099
– ident: 623090r28
  doi: 10.1016/j.hydromet.2018.06.014
– ident: 623090r8
– ident: 623090r15
  doi: 10.1016/j.matlet.2022.131950
– ident: 623090r34
  doi: 10.1016/j.jallcom.2018.05.138
– ident: 623090r23
  doi: 10.1016/j.ceramint.2015.10.055
– ident: 623090r30
  doi: 10.4028/www.scientific.net/KEM.798.212
– ident: 623090r9
  doi: 10.5604/01.3001.0053.9754
– ident: 623090r33
  doi: 10.1016/j.jallcom.2017.12.175
– ident: 623090r35
  doi: 10.1016/j.physb.2009.09.075
– ident: 623090r31
  doi: 10.1016/j.matchemphys.2013.11.035
– ident: 623090r12
  doi: 10.1016/j.matchemphys.2022.126326
SSID ssj0069129
Score 4.6550255
Snippet The work focuses on preparing and characterising BNT-based ceramics via a solidstate method. To investigate the phase, microstructure, and physical and...
SourceID crossref
SourceType Aggregation Database
Title Impact of sintering time on structure and electrical properties of Pb-free BNT-BKT-SZ ceramics
Volume 125
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3NS8MwFA86L3oQP_GbHDw5Upc2_To6UabDMVmF4cHSdhmK0I5tXvzrfa9p06ITnJfShvY17e9H8l7eRwg5HyexiGyesER6EROuNJkvR5JxYVtw4Zh-hInCDz2n8yTuh_aw5jHF7JJ5bCSfC_NK_oMqtAGumCW7BLJaKDTAOeALR0AYjn_C-E6nOM6w7EMeSoebxaMHQBWGLd0DarebHJAJLr9PsY5qHv8Ws_FUyma7F7B2N2CD52Yip7hJ_ayut9YL1IKOqz6uWeYE5W-oChtWq9wp8EAxbmBow_9jnmZ5DEFft3Vf32T2HqlVct3aj0Ao-jlqNxcLFKaoIrSKMdXzXWa6qli5HnRVunPBLnPRYA66mMgTFAyrhZVVQbk0wLzh1cxVeuu_TWg6zBAMHBQStniIIkIUEaKIVbJmur6Nxnr3UXudHJ_nu9rpDisvOIq4_NGLmh5TU0iCLbJZWBL0StFim6zIdIds1OpL7pIXRRCajakmCEWC0CylmiAU4KMVQWhFEHywIAitCEJLguwRfnsTXHdY2cVwomqXhL_-EmufNNIslQeECi5c32v5I-GaYswdf5Qk3JPCSmA6MGV0SC7-LvdomZuPyXrFoBPSgB8hT0Hpm8dnOVJfyPlWGg
link.rule.ids 315,786,790,27957,27958
linkProvider Colorado Alliance of Research Libraries
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Impact+of+sintering+time+on+structure+and+electrical+properties+of+Pb-free+BNT-BKT-SZ+ceramics&rft.jtitle=Archives+of+materials+science+and+engineering&rft.au=Manotham%2C+S.&rft.au=Butnoi%2C+P.&rft.au=Khieokae%2C+M.&rft.au=Paengchit%2C+P.&rft.date=2024-03-01&rft.issn=1897-2764&rft.volume=125&rft.issue=2&rft_id=info:doi/10.5604%2F01.3001.0054.6751&rft.externalDBID=n%2Fa&rft.externalDocID=10_5604_01_3001_0054_6751
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1897-2764&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1897-2764&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1897-2764&client=summon