The Characterization of Zn 1-X Co x O Thin Films Synthesized by Ultrasonic Spray Deposition with Controlled Visible Light Absorption

• Published in: Advances in materials science Vol. 24; no. 2; pp. 61 - 69
• Main Authors: Charef, Azzeddine, Zitouni, Karima, Benramache, Said, Kadri, Abderrahmane
• Format: Journal Article
• Language: English
• Published: 01.06.2024
• ISSN: 2083-4799; 2083-4799
• DOI: 10.2478/adms-2024-0012

Abstract This work examines the grown of Zn 1-x Co x O films at different Co concentrations at 420°C by ultrasonic spray deposition. The effect of Co concentration of Zn 1-x Co x O films on optical characterization, structure crystallinity and electrical conductivity was studied. Transmission spectra of Zn 1-x Co x O films presented three edges in the visible region, it was observed in the range of 541 and 656 nm of wavelengths, which related to the d-d transitions of Co 2+ ion with 3d 7 high-spin configurations in a tetrahedral crystal field formed by neighboring O 2− ions. The gap energy was found increases after doping by Co to maximum value of 3.373 eV at x=0.04. The Urbach energy minimum was 0.083eV, it is obtained for x=0.01. The sprayed Zn 1-x Co x O films exhibit a wurtzite structure with preferred orientation in the (002) direction. The maximum crystallite size of Zn 1-x Co x O films was 95.61 nm at x=0.06. The maximum electrical conductivity of the Co doped ZnO films was located at x=0.06.