Structural, thermal, and DC conductivity properties of WO 3 –P 2 O 5 glasses doped with B 2 O 3
Abstract In this study, glasses in composition 70WO 3 –(30 − х )P 2 O 5 – х B 2 O 3 (0 ≤ х ≤ 20 mol%) were prepared by melt quenching method. The glass formation, structure, and thermal and electrical properties are discussed. Homogeneous glasses were obtained at x = 0–10 mol% B 2 O 3 , whereas...
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| Published in | International journal of applied glass science Vol. 14; no. 2; pp. 247 - 255 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
01.04.2023
|
| Online Access | Get full text |
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| Abstract | Abstract
In this study, glasses in composition 70WO
3
–(30 −
х
)P
2
O
5
–
х
B
2
O
3
(0 ≤
х
≤ 20 mol%) were prepared by melt quenching method. The glass formation, structure, and thermal and electrical properties are discussed. Homogeneous glasses were obtained at
x
= 0–10 mol% B
2
O
3
, whereas glasses with
x
= 15 and 20 contain microinclusions of WO
3
. The glass transition temperature decreases from 709 to 531.6°C with increasing B
2
O
3
content, as well as the crystallization temperature and the thermal stability. The structure of the glasses was studied by Raman spectroscopy and infrared spectroscopy. The Raman spectra are characterized by a band near 995 cm
−1
, a broad band at 788–800 cm
−1
, and a band near 675 cm
−1
ascribed to vibrations of W–O–P, W–O–W, and P–O–B bonds, respectively. The Fourier‐transform infrared spectra show vibrational bands due to characteristic phosphate and borate groups. Tetrahedral BO
4
units prevail in the structural network. The electrical conductivity of the glasses decreased with
x
content due to the growth of WO
3
‐deficient regions. |
|---|---|
| AbstractList | Abstract
In this study, glasses in composition 70WO
3
–(30 −
х
)P
2
O
5
–
х
B
2
O
3
(0 ≤
х
≤ 20 mol%) were prepared by melt quenching method. The glass formation, structure, and thermal and electrical properties are discussed. Homogeneous glasses were obtained at
x
= 0–10 mol% B
2
O
3
, whereas glasses with
x
= 15 and 20 contain microinclusions of WO
3
. The glass transition temperature decreases from 709 to 531.6°C with increasing B
2
O
3
content, as well as the crystallization temperature and the thermal stability. The structure of the glasses was studied by Raman spectroscopy and infrared spectroscopy. The Raman spectra are characterized by a band near 995 cm
−1
, a broad band at 788–800 cm
−1
, and a band near 675 cm
−1
ascribed to vibrations of W–O–P, W–O–W, and P–O–B bonds, respectively. The Fourier‐transform infrared spectra show vibrational bands due to characteristic phosphate and borate groups. Tetrahedral BO
4
units prevail in the structural network. The electrical conductivity of the glasses decreased with
x
content due to the growth of WO
3
‐deficient regions. |
| Author | Pershina, Svetlana V. |
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| References | e_1_2_8_28_1 e_1_2_8_29_1 e_1_2_8_24_1 e_1_2_8_25_1 e_1_2_8_46_1 e_1_2_8_26_1 e_1_2_8_27_1 e_1_2_8_3_1 e_1_2_8_2_1 e_1_2_8_5_1 e_1_2_8_4_1 e_1_2_8_7_1 e_1_2_8_6_1 e_1_2_8_9_1 e_1_2_8_8_1 e_1_2_8_20_1 e_1_2_8_43_1 e_1_2_8_21_1 e_1_2_8_42_1 e_1_2_8_22_1 e_1_2_8_45_1 e_1_2_8_23_1 e_1_2_8_44_1 Khin SO (e_1_2_8_38_1) 2006; 4 e_1_2_8_41_1 e_1_2_8_40_1 e_1_2_8_17_1 e_1_2_8_18_1 e_1_2_8_39_1 e_1_2_8_19_1 e_1_2_8_13_1 e_1_2_8_36_1 e_1_2_8_14_1 e_1_2_8_35_1 e_1_2_8_15_1 e_1_2_8_16_1 e_1_2_8_37_1 e_1_2_8_32_1 e_1_2_8_10_1 e_1_2_8_31_1 e_1_2_8_11_1 e_1_2_8_34_1 e_1_2_8_12_1 e_1_2_8_33_1 e_1_2_8_30_1 |
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| Snippet | Abstract
In this study, glasses in composition 70WO
3
–(30 −
х
)P
2
O
5
–
х
B
2
O
3
(0 ≤
х
≤ 20 mol%) were prepared by melt quenching method. The glass... |
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| Title | Structural, thermal, and DC conductivity properties of WO 3 –P 2 O 5 glasses doped with B 2 O 3 |
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