Optimization of polyacrylonitrile-cysteine resin synthesis and its selective removal of Cu（Ⅱ） in aqueous solutions
Polyacrylonitrile beads（PAN） cysteine（CS） was synthesized from polyacrylonitrile beads（PAN） and cysteine（CS）.The content of the functional group and the percentage conversion of the functional group of PAN-CS prepared under the optimum condition using response surface methodology（RSM） for the first...
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| Published in | 中国化学快报：英文版 Vol. 28; no. 2; pp. 319 - 323 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
2017
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| Online Access | Get full text |
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| Abstract | Polyacrylonitrile beads（PAN） cysteine（CS） was synthesized from polyacrylonitrile beads（PAN） and cysteine（CS）.The content of the functional group and the percentage conversion of the functional group of PAN-CS prepared under the optimum condition using response surface methodology（RSM） for the first attempt were 3.22 mmol/g and 35.78%.The structure was characterized by ET-IR and elemental analysis.The adsorption properties of the resin for Cu（Ⅱ） were investigated by batch and column experiments.Batch adsorption results suggested that PAN-CS had higher adsorption capability for Cu（Ⅱ）than other metal ions and maximum saturated adsorption capacity was 184.7 mg/g.The resin and its metal complexes were studied by FT-IR.Furthermore,the resin can be eluted easily using 1 mol/L HC1.PAN-CS can provide a potential application for selective removal of copper from waste solution. |
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| AbstractList | Polyacrylonitrile beads（PAN） cysteine（CS） was synthesized from polyacrylonitrile beads（PAN） and cysteine（CS）.The content of the functional group and the percentage conversion of the functional group of PAN-CS prepared under the optimum condition using response surface methodology（RSM） for the first attempt were 3.22 mmol/g and 35.78%.The structure was characterized by ET-IR and elemental analysis.The adsorption properties of the resin for Cu（Ⅱ） were investigated by batch and column experiments.Batch adsorption results suggested that PAN-CS had higher adsorption capability for Cu（Ⅱ）than other metal ions and maximum saturated adsorption capacity was 184.7 mg/g.The resin and its metal complexes were studied by FT-IR.Furthermore,the resin can be eluted easily using 1 mol/L HC1.PAN-CS can provide a potential application for selective removal of copper from waste solution. |
| Author | Yang Chang Chen Shen Pin-Yi Li Lei Fang Zai-Zai Tong Min Min Chun-Hua Xiong |
| AuthorAffiliation | Department of Applied Chemistry, Zhejiang Congshang University, Hangzhou 310012, China Department of Food Science and Human Nutrition, University of Florida, Bldg 475 Newell Drive, FL 32611, USA Zhejiang Provincial Key Laboratory of Fiber Materials and Manufacturing Technology, Hangzhou 310018, China Department of Materials Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China |
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| Notes | 11-2710/O6 Polyacrylonitrile beads（PAN） cysteine（CS） was synthesized from polyacrylonitrile beads（PAN） and cysteine（CS）.The content of the functional group and the percentage conversion of the functional group of PAN-CS prepared under the optimum condition using response surface methodology（RSM） for the first attempt were 3.22 mmol/g and 35.78%.The structure was characterized by ET-IR and elemental analysis.The adsorption properties of the resin for Cu（Ⅱ） were investigated by batch and column experiments.Batch adsorption results suggested that PAN-CS had higher adsorption capability for Cu（Ⅱ）than other metal ions and maximum saturated adsorption capacity was 184.7 mg/g.The resin and its metal complexes were studied by FT-IR.Furthermore,the resin can be eluted easily using 1 mol/L HC1.PAN-CS can provide a potential application for selective removal of copper from waste solution. Chelating resin Cysteine RSM Adsorption Cu（Ⅱ） |
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| Snippet | Polyacrylonitrile beads（PAN） cysteine（CS） was synthesized from polyacrylonitrile beads（PAN） and cysteine（CS）.The content of the functional group and the... |
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| Title | Optimization of polyacrylonitrile-cysteine resin synthesis and its selective removal of Cu（Ⅱ） in aqueous solutions |
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