An efficient method to synthesize TNAD by the nitration of 1,4,5,8- tetraazabicyclo-[4,4,0]-decane with N20s and acidic ionic liquids

• Published in: 中国化学快报：英文版 no. 3; pp. 423 - 426
• Main Author: Xiao-Feng Cao Bin-Dong Li Min Wang
• Format: Journal Article
• Language: English
• Published: 2014
• Subjects: N205; TNAD; 催化活性; 合成; 氮杂双环; 癸烷; 硝化; 酸性离子液体

An experimental study was carried out on the direct nitration of 1,4,5,8-tetraaza-bicyclo-[4,4,0]-decane to synthesize 1,4,5,8-tetranitro-l,4,5,8-tetraazabicyclo-[4,4,0]-decane （TNAD） with N205 catalyzed by acidic ionic liquids. Various ionic liquids, such as [HMim]X, [（CH2）4SO3HMim]X and [Capl]X （X...