Self-assembly behaviors of the cholesteryl trimeric-phenylene vinylene derivative in the H20]THF system

Cholesteryl trimeric phenylene vinylene （ChoI-TPV） has been synthesized and characterized. The self- assembly behaviors of ChoI-TPV in THF/H20 system at different water content （water content： 40% and 80%） and different solute concentration （solute concentration： 1.0 ×10^-5 mol/L and saturated conce...

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Published in中国化学快报：英文版 no. 1; pp. 99 - 103
Main Author Yu-Zhen Zhao Zhen-Lin Zhang Ying Li Xue-Qiang Liu Shi-Min Liu Jin-Ku Yu Hai-Quan Zhang
Format Journal Article
LanguageEnglish
Published 2014
Subjects
三聚
乙烯基
亚苯基
十二烷基硫酸钠
可见分光光度法
胆甾醇
自组装行为
衍生物
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Abstract Cholesteryl trimeric phenylene vinylene （ChoI-TPV） has been synthesized and characterized. The self- assembly behaviors of ChoI-TPV in THF/H20 system at different water content （water content： 40% and 80%） and different solute concentration （solute concentration： 1.0 ×10^-5 mol/L and saturated concentration） were studied using UV-vis spectrophotometry, photoluminescence spectrophotometry, and circular dichroism spectroscopy. Based on an analysis of the UV-vis and photoluminescence spectra, Chol-TPV shows the typical H-type aggregation at saturated concentration in 80% aqueous THF. However, ChoI-TPV shows the non-typical H-type aggregation under other conditions. The circular dichroism signal suggests that the Chol-TPV exists in the right handed helical architectures with high water content at a concentration of 1.0 × 10^-5 mol/L, and a helix inversion was found at saturated concentration.
AbstractList Cholesteryl trimeric phenylene vinylene （ChoI-TPV） has been synthesized and characterized. The self- assembly behaviors of ChoI-TPV in THF/H20 system at different water content （water content： 40% and 80%） and different solute concentration （solute concentration： 1.0 ×10^-5 mol/L and saturated concentration） were studied using UV-vis spectrophotometry, photoluminescence spectrophotometry, and circular dichroism spectroscopy. Based on an analysis of the UV-vis and photoluminescence spectra, Chol-TPV shows the typical H-type aggregation at saturated concentration in 80% aqueous THF. However, ChoI-TPV shows the non-typical H-type aggregation under other conditions. The circular dichroism signal suggests that the Chol-TPV exists in the right handed helical architectures with high water content at a concentration of 1.0 × 10^-5 mol/L, and a helix inversion was found at saturated concentration.
Author Yu-Zhen Zhao Zhen-Lin Zhang Ying Li Xue-Qiang Liu Shi-Min Liu Jin-Ku Yu Hai-Quan Zhang
AuthorAffiliation State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China College of Information Science and Engineering and Key Laboratory for Special Fiber and Fiber Sensor of Hebei Province, Yanshan University, Qinhuangdao 066004, China
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Notes 11-2710/O6
Cholesteryl trimeric phenylene vinylene （ChoI-TPV） has been synthesized and characterized. The self- assembly behaviors of ChoI-TPV in THF/H20 system at different water content （water content： 40% and 80%） and different solute concentration （solute concentration： 1.0 ×10^-5 mol/L and saturated concentration） were studied using UV-vis spectrophotometry, photoluminescence spectrophotometry, and circular dichroism spectroscopy. Based on an analysis of the UV-vis and photoluminescence spectra, Chol-TPV shows the typical H-type aggregation at saturated concentration in 80% aqueous THF. However, ChoI-TPV shows the non-typical H-type aggregation under other conditions. The circular dichroism signal suggests that the Chol-TPV exists in the right handed helical architectures with high water content at a concentration of 1.0 × 10^-5 mol/L, and a helix inversion was found at saturated concentration.
Cholesteryl phenylene vinylene Self-assembly Helical architectures
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PublicationTitle 中国化学快报：英文版
PublicationTitleAlternate Chinese Chemical Letters
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Snippet Cholesteryl trimeric phenylene vinylene （ChoI-TPV） has been synthesized and characterized. The self- assembly behaviors of ChoI-TPV in THF/H20 system at...
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StartPage 99
SubjectTerms 三聚
乙烯基
亚苯基
十二烷基硫酸钠
可见分光光度法
胆甾醇
自组装行为
衍生物
Title Self-assembly behaviors of the cholesteryl trimeric-phenylene vinylene derivative in the H20]THF system
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