Construction of Two Chiral Bilayer Coordination Polymers Based on 2-（Pyridine-3-yl）-lH-4,5- imidazoledicarboxylate Ligand

• Published in: 高等学校化学研究：英文版 no. 1; pp. 6 - 9
• Main Author: ZHOU Xiao-ying JING Xue-min XU Da YAN Wei-wei LI Guang-hua ZHANG Li-rong
• Format: Journal Article
• Language: English
• Published: 2013
• Subjects: 双层结构; 吡啶; 手性; 水热条件; 螺旋链; 超分子结构; 配位聚合物; 配体

Two novel isomorphic coordination polymers [Zn（HPyImDC）H20]（1） and [Co（HPylmDC）H20]（2） were synthesized from 2-（pyridine-3-yl）-lH-4,5-imidazoledicarboxylic acid（H3PylmDC） under hydrothermal conditions. Both the compounds crystallized in P21221 chiral space group, possessing left-hand helical chains...