Construction of Two Chiral Bilayer Coordination Polymers Based on 2-（Pyridine-3-yl）-lH-4,5- imidazoledicarboxylate Ligand
Two novel isomorphic coordination polymers [Zn（HPyImDC）H20]（1） and [Co（HPylmDC）H20]（2） were synthesized from 2-（pyridine-3-yl）-lH-4,5-imidazoledicarboxylic acid（H3PylmDC） under hydrothermal conditions. Both the compounds crystallized in P21221 chiral space group, possessing left-hand helical chains...
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| Published in | 高等学校化学研究：英文版 no. 1; pp. 6 - 9 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
2013
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Two novel isomorphic coordination polymers [Zn（HPyImDC）H20]（1） and [Co（HPylmDC）H20]（2） were synthesized from 2-（pyridine-3-yl）-lH-4,5-imidazoledicarboxylic acid（H3PylmDC） under hydrothermal conditions. Both the compounds crystallized in P21221 chiral space group, possessing left-hand helical chains and right-hand helical chains. Two types of helical chains connected with each other to form an interesting 2D bilayer structure which extended to a 3D supermolecular structure via the hydrogen-bonding interactions. Topology analysis shows that H3PylmDC ligand and metal center can be regarded as 3-connected T-shaped nodes, thus leading to a （3,3）- connected network with vertex symbol of （82.10）. |
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| AbstractList | Two novel isomorphic coordination polymers [Zn（HPyImDC）H20]（1） and [Co（HPylmDC）H20]（2） were synthesized from 2-（pyridine-3-yl）-lH-4,5-imidazoledicarboxylic acid（H3PylmDC） under hydrothermal conditions. Both the compounds crystallized in P21221 chiral space group, possessing left-hand helical chains and right-hand helical chains. Two types of helical chains connected with each other to form an interesting 2D bilayer structure which extended to a 3D supermolecular structure via the hydrogen-bonding interactions. Topology analysis shows that H3PylmDC ligand and metal center can be regarded as 3-connected T-shaped nodes, thus leading to a （3,3）- connected network with vertex symbol of （82.10）. |
| Author | ZHOU Xiao-ying JING Xue-min XU Da YAN Wei-wei LI Guang-hua ZHANG Li-rong |
| AuthorAffiliation | State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China; Faculty of Chemistry and Material Science, Langfang Teachers College, Langfang 065000, P. R. China,＂ College of Science, Changchun Institute of Technology, Changchun 130012, P. R. China |
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| Notes | Isomorphic; Helical chain; 2D Bilayer; Hydrogen-bonding; Fluorescence Two novel isomorphic coordination polymers [Zn（HPyImDC）H20]（1） and [Co（HPylmDC）H20]（2） were synthesized from 2-（pyridine-3-yl）-lH-4,5-imidazoledicarboxylic acid（H3PylmDC） under hydrothermal conditions. Both the compounds crystallized in P21221 chiral space group, possessing left-hand helical chains and right-hand helical chains. Two types of helical chains connected with each other to form an interesting 2D bilayer structure which extended to a 3D supermolecular structure via the hydrogen-bonding interactions. Topology analysis shows that H3PylmDC ligand and metal center can be regarded as 3-connected T-shaped nodes, thus leading to a （3,3）- connected network with vertex symbol of （82.10）. 22-1183/06 |
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| Snippet | Two novel isomorphic coordination polymers [Zn（HPyImDC）H20]（1） and [Co（HPylmDC）H20]（2） were synthesized from 2-（pyridine-3-yl）-lH-4,5-imidazoledicarboxylic... |
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| SubjectTerms | 双层结构 吡啶 手性 水热条件 螺旋链 超分子结构 配位聚合物 配体 |
| Title | Construction of Two Chiral Bilayer Coordination Polymers Based on 2-（Pyridine-3-yl）-lH-4,5- imidazoledicarboxylate Ligand |
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